Showing papers in "Inorganic Chemistry Communications in 2009"

TL;DR: The fern-like 1D coordination polymer, [K(2-PTA)(H2O)]n (1), which is constructed by an inorganic skeleton chain [KO2]n with organic 2PTA wings on both sides, has been synthesized and characterized by single crystal X-ray crystallography and dielectric constant measurement as mentioned in this paper.

TL;DR: A coumarin Shiff-base derivative, 7-hydroxy-3-(2-hydroxbenzylideneamino)-2H-chromen-2-one (CSB), was obtained by simple two-step organic synthesis from cheap and commercially available starting materials.

TL;DR: In this article, a coumarin derivative L was synthesized, and the binding property of the L towards metal ions was examined through the changes in fluorescence intensity, which exhibited high selectivity for Fe3+ in HEPES aqueous buffer (pH 7.2).

TL;DR: The first structurally characterized arene-ruthenium half-sandwich complex with a thiosemicarbazone ligand is reported, and their biological activity investigated.

TL;DR: In this paper, the neodymium complex is one of the rare bipyrimidine-bridged dinuclear complexes and the absorption spectrum displays characteristic hypersensitive as well as non-hypersensitive transitions.

TL;DR: In this paper, a new class of cyclometallated ruthenium(II) complexes, Ru(tctpy)(C^N)(NCS) ( 1, 2 ), where C^N is a bidentate cyclometric ligand such as 2-phenylpyridinato or 2-(4-(2-phenylethynyl)phenyl)pyrinato, was synthesized.

TL;DR: A triarylmethane dye 1 detects CN− from water and shows remarkable selectivity over other anions and dramatic color changes, in solution as well as when dyed as mentioned in this paper.

TL;DR: In this article, the reaction of uranyl nitrate with pyridine-2-carboxylic acid (HL1) under hydrothermal conditions gives the complex [(UO2)3(L1)4(NO3)2], which differs from the previously reported molecular complex, obtained at room temperature, by the absence of water, coordinated and free, and the extended carboxylate bridging.

TL;DR: In this article, an hydrazone Schiff base-iron (III) complex using salicylidene benzoyl hydrazine (L) as ligand has been synthesized and characterized by elemental analyses, IR, 1H and 13C NMR and UV-Vis spectroscopy.

TL;DR: A new fluorescence macrocyclic receptor based on the Zn(II) complex of a C 2 -terpyridine and a crown ether was developed for molecular recognition of zwitterionic amino acids in water/DMF solution as discussed by the authors.

TL;DR: In this article, three 4d-4f heterometallic polymers, Ln2Ag2(Hpydc)2(Pydc), 2(pydC) 2(ox), 4H2O (Ln = Nd (1), Eu (2) and Er (3), have been successfully synthesized under hydrothermal condition and structurally characterized.

TL;DR: In this article, the reaction of Ag2O with a mixture of benzene-1,3,5-tricarboxylic acid (H3BTC) and 2-aminopyrazine (APYZ) under the ammoniacal conditions gives rise to a novel metal-organic coordination polymer Ag6(BTC)2(APyZ)6·9H2O (1).

TL;DR: In this article, easily available N,N-dimethyldipyrromethane (1) demonstrates a high chromogenic selectivity for Cu2+ over other cations with detection limit 4.76

TL;DR: In this article, three 3D-4f isostructural heterometallic coordination polymers, namely [Ln2Zn(2,3-pydc)4(H2O)4·4H 2O]n, were synthesized by the hydrothermal reactions of Ln2O3.

TL;DR: The first structurally characterized dicyano Fe(II) porphyrins in a highly distorted and sterically crowded macocyclic environment were reported in this article.

TL;DR: In this paper, a ruthenium(II)polypyridine complex (1) having a 2,6-bis (4-carboxyquinolin-2-yl) pyridine ligand was synthesized as a sensitizer for dye-sensitized solar cells (DSCs).

TL;DR: In this paper, a solution phase reaction of AgNO3 with a mixture of benzene-1,3,5-tricarboxylic acid (H3BTC) and heterocyclic 2-aminopyrimidine (APYM) under the ammoniacal conditions gives rise to a novel metal-organic coordination polymer Ag3(BTC)2 (1), which possesses a unique three-dimensional (3D) framework with one-dimensional channels surrounded by carboxylato-supported Ag-Ag dimers, Ag chains, fully deprotonated

TL;DR: In this paper, two d10 coordination polymers, Zn(Beta)2 (1) and Cd2(Beta)-3Cl(H2O) (Hbeta= 5-benzyl-tetrazole) have been synthesized by the in situ [3 + 2] cycloaddition reaction of 5-bensylacetonitrile, sodium azide and MCl2 [M = Zn (1); M = Cd (2)] under hydrothermal condition.

TL;DR: In this paper, a novel 2D coordination polymer, formulated as [Cd2(Hpimdc)2(bpp)(H2O)]n (bpp = 1,3-bis(4-pyridyl)propane, H3Pimdc = 2-propyl-4,5-imidazoledicarboxylate), has been hydro-thermally synthesized and structurally characterized, which shows unusual multifarious helical structures and (3,4)-connected network with (4.82)2

TL;DR: In this paper, the results reveal that 1 has a three-dimensional framework containing Sm2Mn4 clusters and the luminescence and magnetic properties of 1 were also investigated.

TL;DR: In this paper, the reaction of Cu(ClO4)2, 2-pyridylcarbonyl-N, N-bis(2-polypyrinylmethyl)amine (DPA-CO-py) and sodium dicyanamide (Nadca) in aqueous medium led to the isolation of three complexes: {[Cu(DPA)(μ 1,5-dca)]ClO 4n (1), [Cu2(pic)2(μ1,3-H2NCO-N-

TL;DR: An unprecedented linear supramolecular manganese(III)-lithium(I) coordination polymer, [MnIIIL(OH)2LiI]n, has been prepared and structurally characterized as mentioned in this paper.

TL;DR: In this article, the facile, rapid, and effective synthesis of coordination polymer La(1,3,5-BTC)(H2O)6 has been realized via direct precipitation at room temperature.

TL;DR: In this article, the luminescent property of complex 1 was discussed and three 3D open heterometallic coordination frameworks were constructed from rare zigzag lanthanide-ox-silver chains and nic linkers.

TL;DR: In this article, the P-handed and M-handed helical chains interweave mutually into a novel 3D coordination framework with diamondoid skeleton, and the photoluminescent property and thermal stability of 1 were also discussed.

TL;DR: A lead-II orotate complex was synthesized under hydrothermal condition and characterized by X-ray diffraction, IR, solid-state photoluminescence and thermogravimetric analysis as discussed by the authors.

TL;DR: A novel polyoxotungstate cluster (H2en)2.5H9[Fe6Ge3W24O94(H2O)2]· 14.14 H2O (1) (en =ethylenediamine) has been hydrothermally synthesized and structurally characterized by IR, TGA and single-crystal X-ray diffraction as mentioned in this paper.

TL;DR: In this article, the authors showed that the linker flexibility of two Salen-type Schiff-base ligands (H2L1 and H2L2) resulted in the difference of structures and NIR luminescent properties of their mixed-ligands complexes.

TL;DR: An original Schiff-base type fluorescent chemosensor 1-phenyl-3-methyl-5-hydroxypyrazole-4-carbaldehyde(benzoyl)hydrazone (H2L) for Cu2+ has been designed and synthesized as discussed by the authors.

TL;DR: The first examples of indium(III) derivatives based on sterically hindered 4,6-di-tert-butyl-N-(2,6di-iso-propylphenyl)-o-iminobenzoquinone (imQ) were synthesized and characterized in details as mentioned in this paper.