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Determination of banned azo dyes in consumer goods

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TLDR
In this article, an overview of the state of development of analytical procedures for the determination of such azo dyes, which are banned by the European Commission, can be found.
Abstract
Azo dyes, extensively used for coloring a variety of consumer goods, such as leather, clothes, food, and toys, can under certain conditions be reduced to form confirmed or suspected carcinogenic aromatic amines. This article gives an overview of the state of development of analytical procedures for the determination of such azo dyes, which are banned by the European Commission.

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Citations
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Journal ArticleDOI

Structure–properties relationships investigation on the azo dyes derived from benzene sulfonamide intermediates

TL;DR: In this paper, the properties of derived azo dyes derived from azo intermediates were characterized by FTIR, MS and 1H NMR, which revealed that their molecular configuration is non-planar.
Journal ArticleDOI

Simultaneous determination of 11 restricted dyes in cosmetics by ultra high-performance liquid chromatography/tandem mass spectrometry

TL;DR: In this article, a simple, fast, and sensitive method was developed for the simultaneous determination of 11 restricted water-soluble colorants (including Tartrazine, Amaranth, Ponceau 4RC, Sunset Yellow, Allura Red AC, Acid Red 2G,Ponceau SX, Brilliant Blue FCF, Orange I, Acid Black 1, and Acid Orange 7) in eye shadow, lipstick, lip gloss, and other cosmetics by using ultra-high performance liquid chromatography/tandem mass spectrometry.
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Liquid phase microextraction based sensitive analytical strategy for the determination of 22 hazardous aromatic amine products of azo dyes in wastewater and tap water samples by GC-MS system

TL;DR: In this paper, the authors presented a comprehensive optimization and validation of a dispersive liquid-liquid microextraction (DLLME) method for the preconcentration of 22 aromatic amines in gas chromatography spectrometry system.
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Thermal behaviour of CODA azoic dye liquid crystal and nanostructuring by drop cast and spin coating techniques

TL;DR: In this article, the thermal analysis of CODA dye was performed in air flow and nitrogen flow atmospheres by means of simultaneous thermogravimetry TG, derivative thermograves DTG, differential thermal analysis DTA and differential scanning calorimetry DSC.
References
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Journal ArticleDOI

Comments on the history and importance of aromatic and heterocyclic amines in public health.

TL;DR: Investigation on the mode of action of this class of chemicals, identified as heterocyclic amines (HCAs), found that HCAs induced cancer in rats in these organs and also in the prostate and the pancreas, and there is some evidence that they affect the vascular system.
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Aromatic amines and cancer

TL;DR: The consistent observation of a difference between men and women in bladder cancer risk, after allowing for known risk factors, suggests consideration of gender-related biological determinants for future investigation.
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Mutagenicity of azo dyes used in foods, drugs and cosmetics before and after reduction by Clostridium species from the human intestinal tract

TL;DR: No mutagenicity was induced in either TA98 or TA100 by any of the seven azo dyes or the reduced metabolites when tested at concentrations as high as 200 microg/plate, with or without exogenous metabolic activation by rat liver fraction S-9.
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Formation of a carcinogenic aromatic amine from an azo dye by human skin bacteria in vitro.

TL;DR: The ability to cleave azo dyes seems to be widely distributed among human skin bacteria, as, under these in vitro conditions, bacteria isolated from healthy human skin and human skinacteria from strain collections also exhibited azo reductase activity.
Journal ArticleDOI

Mutagenicity and carcinogenicity of aromatic amines metabolically produced from Azo Dyes

TL;DR: In this article, the authors investigated the carcinogenicity of aromatic amines metabolically produced from Azo Dyes and found that they are mutagenous and carcinogenous.
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