Journal ArticleDOI
Development and Application of the Dispersive Solid-Phase Extraction Method Based on Molecular Imprinted Polymers for Removal of Matrix Components of Bivalve Shellfish Extracts in the GC–MS/MS Analysis of Amide/Dinitroaniline/Substituted Urea Herbicides
Xinru Yu,Ze-Ming Zhang,Wei Li,Zhang Rongrong,Hai-Feng Jiao,Jian Zhao,Aili Sun,Xizhi Shi,Jiong Chen +8 more
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TLDR
A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) sample preparation method coupled with gas chromatography-tandem mass spectrometry has been developed for the simultaneous analysis of amide/dinitroaniline/substituted urea herbicides in bivalve shellfish samples.Abstract:
A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) sample preparation method coupled with gas chromatography–tandem mass spectrometry has been developed for the simultaneous analysis of amide/dinitroaniline/substituted urea herbicides in bivalve shellfish samples. A molecularly imprinted polymer (MIP) synthesized through bulk polymerization exhibited strong group–selective interactions with pigments, including β-carotene, chlorophyll A, and fucoxanthin, in bivalve shellfish extracts. Afterward, a modified QuEChERS method based on MIPs and primary and secondary amines was established to effectively remove matrix components in bivalve shellfish samples. Under the optimal conditions, good linearities were obtained in all of the analytes with R2 larger than 0.9995. Limits of quantification were in the range of 0.03–8.88 μg kg−1, respectively. The recoveries of all of the herbicides spiked at three concentrations of 10, 25, and 50 μg kg−1 in blank bivalve shellfish samples ranged from 81 to 109% with intra-day and inter-day relative standard deviations less than 8%, respectively. Results demonstrated that the proposed QuEChERS method coupled with GC–MS/MS was applied successfully to simultaneously determine 26 amide/dinitroaniline/substituted urea herbicides in bivalve shellfish.read more
Citations
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Journal ArticleDOI
Sample Preparation Using Molecularly Imprinted Polymers.
TL;DR: The new strategies of development of MIPs in different formats dedicated to various extraction methods often treated independently are reviewed, for both small organic molecules and proteins for which there are high expectations for replacing antibodies.
Journal ArticleDOI
Effective removal matrix interferences by a modified QuEChERS based on the molecularly imprinted polymers for determination of 84 polychlorinated biphenyls and organochlorine pesticides in shellfish samples
TL;DR: A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) procedure combined with GC-MS/MS detection approach using a dynamic multiple reaction monitoring (DMRM) mode was successfully applied for the simultaneous analysis of 84 polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in shellfish samples.
Journal ArticleDOI
Surrogate Imprinting Strategies: Molecular Imprints via Fragments and Dummies
TL;DR: There is an increasing need to selectively bind, determine, preconcentrate, or filter compounds frequently present at very low concentration levels in a wide variety of complex matrices as mentioned in this paper.
Journal ArticleDOI
Molecularly imprinted polymers for miniaturized sample preparation techniques: strategies for chromatographic and mass spectrometry methods
TL;DR: A review of molecularly imprinted polymers (MIPs) can be found in this paper, with priority given to the small scale for applications in clinical and environmental analyses.
Journal ArticleDOI
Molecularly Imprinted Polymers for Dispersive (Micro)Solid Phase Extraction: A Review
TL;DR: In this paper, a review describes the development of batch solid phase extraction procedures based on dispersive (micro)solid phase extraction with molecularly imprinted polymers (MIPs) and magnetic MIPs.
References
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Fast and Easy Multiresidue Method Employing Acetonitrile Extraction/Partitioning and "Dispersive Solid-Phase Extraction" for the Determination of Pesticide Residues in Produce
TL;DR: A simple, fast, and inexpensive method for the determination of pesticide residues in fruits and vegetables is introduced and effectively removes many polar matrix components, such as organic acids, certain polar pigments, and sugars, to some extent from the food extracts.
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Carotenoid Pigments in Seafoods and Aquaculture
TL;DR: Carotenoids contribute to the yellow, orange, and red colors of the skin, shell, or exoskeleton of aquatic animals and are the most widespread pigments found in nature.
Journal ArticleDOI
A review of recent developments and trendsin the QuEChERS sample preparation approach
Tomasz Rejczak,Tomasz Tuzimski +1 more
TL;DR: A comprehensive review of the recent developments and trends in the QuEChERS (quick, easy, cheap, effective, rugged, and safe) sample preparation approach is presented in this paper, where the authors introduce various modifications based on the use of different extraction solvent and salt formulation and buffer additions for salting-out partitioning step and the application of various d-SPE sorbents for clean-up step.
Journal ArticleDOI
Characterization of binding sites in molecularly imprinted polymers
TL;DR: A review of the progress of the understanding of the molecular recognition binding sites beyond the usual description of adsorption isotherms is given in this article, where analytical and numerical methods used for calculating the adsorbing isotherm and the adsoreption energy distribution, as a quantitative measure of the imprinted polymer heterogeneity, are also discussed.