Journal ArticleDOI
Dimethyloxosulfonium Methylide ((CH3)2SOCH2) and Dimethylsulfonium Methylide ((CH3)2SCH2). Formation and Application to Organic Synthesis
E. J. Corey,Michael Chaykovsky +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1965-03-01. It has received 1315 citations till now. The article focuses on the topics: Trimethylsulfoxonium iodide & Organic synthesis.read more
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Stereoselective Cyclopropanation Reactions
TL;DR: This review will focus mainly on the new methods that have appeared in the literature since 1989 for stereoselective cyclopropanation reactions from olefins: the halomethylmetal-mediated cycloalkane reactions, the transition metal-catalyzed decomposition of diazo compounds, and the nucleophilic addition-ring closure sequence.
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Enantioselective catalytic aziridinations and asymmetric nitrene insertions into CH bonds.
Paul Müller,Corinne Fruit +1 more
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Catalytic C-C bond-forming multi-component cascade or domino reactions: pushing the boundaries of complexity in asymmetric organocatalysis.
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A new golden age for donor-acceptor cyclopropanes.
TL;DR: This Review highlights the appropriate tools for successfully employing donor-acceptor cyclopropanes in ring-opening reactions, cycloadditions, and rearrangements.