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Dipolar Nature of Molecular Complexes Formed in the Excited State
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This article is published in Journal of Chemical Physics.The article was published on 1967-08-01. It has received 256 citations till now. The article focuses on the topics: Excited state.read more
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Kinetics of Fluorescence Quenching by Electron and H‐Atom Transfer
Dieter Rehm,Albert Weller +1 more
TL;DR: In this article, the rate constants of 60 typical electron donor-acceptor systems have been measured in de-oxygenated acetonitrile and are shown to be correlated with the free enthalpy change, ΔG23, involved in the actual electron transfer process.
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Enthalpy-entropy compensation phenomena in water solutions of proteins and small molecules: a ubiquitous property of water.
Rufus Lumry,Shyamala Rajender +1 more
TL;DR: It is tentatively concluded that the pattern is real, very common and a consequence of the properties of liquid water as a solvent regardless of the solutes and the solute processes studied, and that liquid water plays a direct role in many protein processes and may be a common participant in the physiological function of proteins.
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Photoinduced Electron Transfer in Solution: Exciplex and Radical Ion Pair Formation Free Enthalpies and their Solvent Dependence
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Invited review solvatochromic shifts: The influence of the medium on the energy of electronic states
TL;DR: In this paper, a number of examples of solvatochromic shifts are shown and discussed according to the various solute-medium interactions, and some limitations of the theories of solvent shifts and possible improvements are discussed.
Journal ArticleDOI
Highly efficient luminescence from space-confined charge-transfer emitters.
Xun Tang,Lin-Song Cui,Hong-Cheng Li,Alexander J. Gillett,Florian Auras,Yang-Kun Qu,Cheng Zhong,Saul T. E. Jones,Zuo-Quan Jiang,Richard H. Friend,Liang-Sheng Liao +10 more
TL;DR: The use of rigid linkers to control the relative position and interaction of donor and acceptor units in exciplex emitters leads to the realization of organic light-emitting devices with enhanced external quantum efficiency.
References
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Theory of Solvent Effects on Molecular Electronic Spectra. Frequency Shifts
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Luminescence of Organic and Inorganic Materials
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Elektronenübertragungsreaktionen des angeregten Perylens
Horst Leonhardt,Albert Weller +1 more
TL;DR: In this paper, angeregten Molekulen and geeigneten Elektronendonatoren moglich, die im Grundzustand nicht stattfinden.
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The theory of the electronic spectra of aromatic hydrocarbon dimers
J.N. Murrell,J. Tanaka,J. Tanaka +2 more
TL;DR: In this article, the changes of the electronic transition energies which occur on dimerization of naphthalene, anthracene, pyrene and perylene have been calculated, and good agreement between the observed and calculated fluorescence spectrum is obtained if it is assumed that in the fluorescent state of the dimer the interplanar separation of the monomers is approximately 3 a.