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Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site

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This article is published in Nature Materials.The article was published on 2022-06-30. It has received 37 citations till now. The article focuses on the topics: Medicine & Methane monooxygenase.

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Hydrogen-Bonded Organic Framework Ultrathin Nanosheets for Efficient Visible Light Photocatalytic CO2 Reduction.

TL;DR: In this article , a post-modification of robust guanine-quadruplex-linked 2,2'-pyridine-containing HOF-25 with Ni(ClO) 4 ·6H 2 O followed by exfoliation using sonication method affords hydrogen-bonded organic framework (HOF) nanosheets (NSs) of HOF25-Ni in the yeild of 56%.
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Crystalline MoS2 enhanced conductive black titania for efficient solar to chemical conversions: photocatalytic CO2 reduction and CH4 oxidation

TL;DR: In this article , a facile direct solid-state reaction strategy employing crystalline MoS2 coupled conductive black titania (BT) to create nanocomposites with BT−MoS2 substantial synergy was reported.
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Targeted H2O activation to manipulate the selective photocatalytic reduction of CO2 to CH3OH over carbon nitride supported cobalt sulfide

TL;DR: In this paper , the selective photocatalytic reduction of CO2 by H2O to methanol is a desirable solution for solar energy storage with production of abundant chemicals.
Journal ArticleDOI

Bimetallic dual-atom catalysts: A step toward bioinspired catalysis

Xue Han, +1 more
- 01 Oct 2022 - 
TL;DR: In this paper , Lo et al. developed a reliable assembly approach to solve the problem of mimicking bimetallic centers using synthetic materials, which will require precise control of the distribution and local environment of each active site.
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Direct photocatalytic conversion of methane to value-added chemicals

Huidong Song, +1 more
- 01 Sep 2022 - 
TL;DR: In this article , the authors present the latest advances in direct photocatalytic conversion of methane to liquid oxygenates and higher hydrocarbons, with an emphasis on the strategies for the rational design of photatalysts to improve the activity and selectivity of the desired products.
References
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Journal ArticleDOI

EasySpin, a comprehensive software package for spectral simulation and analysis in EPR.

TL;DR: EasySpin provides extensive EPR-related functionality, ranging from elementary spin physics to data analysis, and provides routines for the simulation of liquid- and solid-state EPR and ENDOR spectra.
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Spin trapping: ESR parameters of spin adducts.

TL;DR: In this article, the electron spin resonance hyperfine splitting constants of spin adducts of interest in this area are tabulated and a brief comment on the source of the radical trapped is given.
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Platinum Catalysts for the High-Yield Oxidation of Methane to a Methanol Derivative

TL;DR: Mechanistic studies show that platinum(II) is the most active oxidation state of platinum for reaction with methane, and are consistent with reaction proceeding through carbon-hydrogen bond activation of methane to generate a platinum-methyl intermediate that is oxidized to generate the methyl ester product.
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Red-, blue-, or no-shift in hydrogen bonds: a unified explanation.

TL;DR: This explanation organizes hydrogen bonds (HBs) with a seemingly random relationship between the X-H bond length (and IR frequency and its intensity) to its interaction energy.
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