Journal ArticleDOI
Dynamic polymer blends—component recombination between neat dynamic covalent polymers at room temperature
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TLDR
Dynamic polymers based on acylhydrazone bonds in the linear main chains were found to show bond exchange leading to crossover component recombination as neat polymers even at room temperature under acid catalysis, thus generating randomized copolymers.About:
This article is published in Chemical Communications.The article was published on 2005-03-15. It has received 130 citations till now. The article focuses on the topics: Polymer & Polymer blend.read more
Citations
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Dynamic combinatorial chemistry.
Peter T. Corbett,Julien Leclaire,Laurent Vial,Kevin R. West,Jean-Luc Wietor,Jeremy K. M. Sanders,Sijbren Otto +6 more
Journal ArticleDOI
From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry
TL;DR: Supramolecular chemistry considers chemical objects and systems capable of responding to external solicitations by modification of their constitution through component exchange or reorganisation, and opens the way towards an adaptive and evolutive chemistry, a further step towards the chemistry of complex matter.
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Using the dynamic bond to access macroscopically responsive structurally dynamic polymers
TL;DR: The emergence of a new trend in the design of adaptive materials that involves the use of reversible chemistry to programme a response that originates at the most fundamental (molecular) level is described.
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Self-healing polymeric materials
Ying Yang,Marek W. Urban +1 more
TL;DR: This review outlines the recent advances in the field of self-healing polymers, and the primary classes are the covalent bonding, supramolecular assemblies, ionic interactions, chemo-mechanical self- healing, and shape memory polymers.
References
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Journal ArticleDOI
A Thermally Re-mendable Cross-Linked Polymeric Material
Xiangxu Chen,Matheus Adrianus Dam,Kanji Ono,Ajit Mal,Hongbin Shen,Steven Nutt,Kevin Sheran,Fred Wudl +7 more
TL;DR: A transparent organic polymeric material that can repeatedly mend or “re-mend” itself under mild conditions and is a tough solid at room temperature and below with mechanical properties equaling those of commercial epoxy resins.
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Toward Self-Organization and Complex Matter
TL;DR: The field of supramolecular chemistry aims at developing highly complex chemical systems from components interacting through noncovalent intermolecular forces as mentioned in this paper, and has been a major field of research in biology and physics.
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Dynamic covalent chemistry.
Stuart J. Rowan,Stuart Cantrill,Graham R. L. Cousins,Jeremy K. M. Sanders,J. Fraser Stoddart +4 more
TL;DR: Some recent examples where dynamic covalent chemistry has been demonstrated are shown to emphasise the basic concepts of this area of science.
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Toward complex matter: supramolecular chemistry and self-organization.
TL;DR: As the wind of time blows into the sails of space, the unfolding of the universe nurtures the evolution of matter under the pressure of information.
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Dynamic Combinatorial Chemistry and Virtual Combinatorial Libraries
TL;DR: The thermodynamically-driven evolution of the system leads to the actual expression of the constituent(s) that present the best binding to/molecular recognition with the target site.