Journal ArticleDOI
Eine Reihe definierter Metathesekatalysatoren – Synthese von und Reaktionen mit [RuCl2 ( CHR′)(PR3)2]
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This article is published in Angewandte Chemie.The article was published on 1995-09-15. It has received 269 citations till now.read more
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Dynamic covalent chemistry.
Stuart J. Rowan,Stuart Cantrill,Graham R. L. Cousins,Jeremy K. M. Sanders,J. Fraser Stoddart +4 more
TL;DR: Some recent examples where dynamic covalent chemistry has been demonstrated are shown to emphasise the basic concepts of this area of science.
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Olefin Metathesis and Beyond
TL;DR: In this paper, the authors provide an overview of the development of catalysts for olefin metathesis which combine high activity, durability, and excellent tolerance towards polar functional groups.
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Metathesis Reactions in Total Synthesis
Kyriacos C. Nicolaou,Kyriacos C. Nicolaou,Paul G. Bulger,Paul G. Bulger,David Sarlah,David Sarlah +5 more
TL;DR: Examples of total syntheses in which metathesis reactions of olefins, enynes, and alkynes played a crucial role and which imparted to these endeavors certain elements of novelty, elegance, and efficiency are highlighted.
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Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture)
TL;DR: This is a story of the exploration of the olefin-metathesis reaction, a reaction that has been the major emphasis of my independent research and contributed to oleFin metathesis becoming the indispensable synthetic tool that it is today.
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Oils and Fats as Renewable Raw Materials in Chemistry
TL;DR: The remarkable advances made during the last decade in organic synthesis, catalysis, and biotechnology using plant oils and the basic oleochemicals derived from them will be reported, including, for example, ω-functionalization of fatty acids containing internal double bonds, application of the olefin metathesis reaction, and de novo synthesis of fatty fatty acids from abundantly available renewable carbon sources.
References
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Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media
TL;DR: In this paper, an Ru(II) complex with a strained olefin was used to produce a carbene species that polymerizes norbornene in organic media both in the absence and presence of protic/aqueous solvents.
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Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes
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Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts
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Catalytic ring-closing metathesis of functionalized dienes by a ruthenium carbene complex
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Polymer synthesis and organotransition metal chemistry.
Robert H. Grubbs,William Tumas +1 more
TL;DR: The recent development of living coordinative polymerization systems has led to the preparation of a number of new, interesting materials, including block copolymers, conducting polymers or precursors, and ionophoric polymeric substrates.