Journal ArticleDOI
Evolution And Synthetic Applications Of The Heck-matsuda Reaction: The Return Of Arenediazonium Salts To Prominence
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In this paper, the authors highlight the potential and the versatility of arenediazonium salts as viable alternatives to conventional aryl halides and oxygen-based electrophiles for Pd-catalyzed Heck reactions.About:
This article is published in European Journal of Organic Chemistry.The article was published on 2011-03-01. It has received 245 citations till now. The article focuses on the topics: Heck–Matsuda reaction & Heck reaction.read more
Citations
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Journal ArticleDOI
The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light
Durga Prasad Hari,Burkhard König +1 more
TL;DR: The origins of this reaction and its scope and applications are summarized and the use of photocatalyzed Pschorr cyclization to induce the one-electron reduction and activation of the diazonium salts is summarized.
Journal ArticleDOI
Transition-Metal-Catalyzed Cleavage of C-N Single Bonds.
TL;DR: This paper presents the results of aalysis experiments conducted at the BNLMS and Nankai University with real-time measurements of the response of the H2O-O2/O2 mixture to E2O/O3 mixture.
Journal ArticleDOI
Recent applications of arene diazonium salts in organic synthesis.
TL;DR: In this review, recent advances involving arene diazonium salts as starting materials or active intermediates for various synthetically useful applications are summarized.
Journal ArticleDOI
Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy
TL;DR: An enantioselective variant that delivers β-, γ-, or δ-aryl carbonyl products from acyclic alkenol substrates is reported, which imparts notable regioselectivity during migratory insertion and promotes the migration of the alkene’s unsaturation toward the alcohol to ultimately form the ketone product.
Journal ArticleDOI
Photoinduced Deaminative Borylation of Alkylamines
TL;DR: An operationally simple deaminative borylation reaction of primary alkylamines has been developed that enables photoinduced single-electron transfer and fragmentation to carbon-centered radicals, which are subsequently borylated.
References
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Journal ArticleDOI
The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.
BookDOI
Handbook of organopalladium chemistry for organic synthesis
TL;DR: Palladium-CATALYZED Reactions Involving Nucleophilic Attack on -Ligands of Palladium-Alkene, PalladiumAlkyne, and Related Derivatives as mentioned in this paper.
Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review
TL;DR: A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki coupling reactions over the last 15 years as mentioned in this paper, and there are now many suggestions in the literature that narrow the scope of types of precatalyst that may be considered true catalysts in these coupling reactions.
Related Papers (5)
Diazonium salts as substrates in palladium-catalyzed cross-coupling reactions.
Reaction of diazonium salts with transition metals. i. arylation of olefins with arenediazonium salts catalyzed by zero valent palladium
Kiyoshi Kikukawa,Tsutomu Matsuda +1 more