Journal ArticleDOI
Facile Rotation around SiSi Double Bonds in Tetrakis(trialkylsilyl)disilenes
Reads0
Chats0
TLDR
In this article, stable disilenes having two different trialkylsilyl substituents [SiASiBSiSiSiASIB ((E)-2 and (Z)-2) and SiA2SiSiSiB2 (3), where SiA = t-BuMe2Si and SiB = i-Pr2MeSi] were prepared and characterized.About:
This article is published in Organometallics.The article was published on 2000-04-08. It has received 42 citations till now. The article focuses on the topics: Isomerization & Disilene.read more
Citations
More filters
Journal ArticleDOI
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
Roland Fischer,Philip P. Power +1 more
TL;DR: The key unifying feature of almost all molecules discussed in this review is that they are generally stabilized by the use of bulky substituents which block associative or various decomposition pathways.
Book ChapterDOI
Progress in the Chemistry of Stable Disilenes
TL;DR: In this article, the authors discuss present advances in novel synthetic methods for various types of stable disilenes, such as cyclic and bicyclic disilene and conjugated tetrasiladienes.
Journal ArticleDOI
Isolable silylene, disilenes, trisilaallene, and related compounds
TL;DR: In this article, a trisilaallene, the first stable compound with formal sp-hybridized silicon atom, was synthesized using the silylene, which was thermally very stable and showed remarkable spiroconjugation between the two ring p systems.
References
More filters
Journal ArticleDOI
Tetramesityldisilene, a stable compound containing a silicon-silicon double bond
TL;DR: Irradiation of 2,2-bis(2,4,6-trimethylphenyl)hexamethyltrisilane in hydrocarbon solution produces tetramesityldisilene, which can be isolated as a yellow-orange solid stable to room temperature and above in the absence of air.
Journal ArticleDOI
Synthesis, structure, and reactivity of extremely hindered disilenes: the first example of thermal dissociation of a disilene into a silylene
Journal ArticleDOI
Stable Tetrakis(trialkylsilyl)disilenes; Synthesis, X-Ray Structures, and UV/VIS Spectra
Journal ArticleDOI
Thermal Dissociation of Disilenes into Silylenes
TL;DR: The first example of cycloaddition of silylenes to aromatic compounds was reported in this paper, where Silylene 2 reacted with naphthalene and benzene to give the corresponding adducts, 15 and 17, respectively, which were confirmed by X-ray crystallographic analyses.