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Journal ArticleDOI

Formation of N‐Sulfonylamidines by Copper‐Catalyzed Coupling of Sulfonyl Azides, Terminal Alkynes, and Trialkylamines.

TLDR
The three-component reaction involves coupling of copper acetylides with azides to give ketimine intermediates which are trapped by trialkylamines to yield the title compounds as mentioned in this paper.
Abstract
The three-component reaction involves coupling of copper acetylides with azides to give ketimine intermediates which are trapped by trialkylamines to yield the title compounds.

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Syntheses of N-sulfonyl-N,N-disubstituted amidines via a three-component free-radical coupling reaction of tertiary amines and arenesulfonyl azides with terminal alkynes

TL;DR: In this article, a facile and efficient synthesis of N-sulfonyl-N,N-disubstituted amidines has been achieved via a CuI-catalyzed three-component free-radical coupling reaction of tertiary amines and arenes sulfonyl azides with terminal alkynes in the presence of azodiisobutyronitrile.
Journal ArticleDOI

1, 3-Dipolarna cikloadicija (II. dio): Trokomponentne Cu(I) katalizirane klik-reakcije

TL;DR: In this paper, kataliziranim reakcijama sulfonil- odnosno fosforil-azida i terminalnih alkina nastaje intermedijar ketenimin koji reagira s nukleofilima kao sto su voda, alkoholi, amini, piroli ili indoli.
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Journal ArticleDOI

Formation of N-sulfonylamidines by copper-catalyzed coupling of sulfonyl azides, terminal alkynes, and trialkylamines

TL;DR: In this paper, a copper-catalyzed synthesis of N-sulfonylamidines via three-component coupling of sulfonyl azides, terminal alkynes, and trialkylamines is reported.
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