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Journal ArticleDOI

Frequency response of unified dielectric and conductive systems involving an exponential distribution of activation energies

J. Ross Macdonald
- 01 Sep 1985 - 
- Vol. 58, Iss: 5, pp 1955-1970
TLDR
In this paper, it is shown that the corresponding response of an associated conductive or dielectric system may be immediately obtained through the use of new duality relations. But the authors do not consider the relationship between the activation energy probability density and the activation frequency response.
Abstract
When the small‐signal ac frequency response of a dielectric or conductive system is known, either functionally or as data, it is shown that the corresponding response of an associated conductive or dielectric system may be immediately obtained through the use of new duality relations. A specific model is considered which involves thermally activated capacitance and/or resistance, with an activation energy probability density exponentially dependent on energy. Previous frequency response analyses of such a continuously distributed model involve inadequate approximations and lead to erroneous predictions. Correct immittance results are presented in three ways: analytically, by means of complex plane plots, and through the use of three‐dimensional perspective plots. Results are given in general form but apply to both dielectric and conductive systems which involve the same functional dependence on activation energies. Low‐ and high‐frequency‐limiting responses for a given system are found to be associated wi...

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Citations
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Journal ArticleDOI

Determination of effective capacitance and film thickness from constant-phase-element parameters

TL;DR: Two different mathematical formulas for estimating effective capacitance from CPE parameters, taken from the literature, are associated unambiguously with either surface or normal time-constant distributions as mentioned in this paper.
Journal ArticleDOI

Enhanced Graphical Representation of Electrochemical Impedance Data

TL;DR: In this article, the authors proposed a graphical approach for electrochemical impedance data using Bode plots, corrected for Ohmic resistance, logarithmic plots of the imaginary component of the impedance, and effective capacitance plots.
Journal ArticleDOI

A review of AC impedance modeling and validation in SOFC diagnosis

TL;DR: In this paper, over 150 journal papers were reviewed with respect to AC impedance modeling and validation in solid oxide fuel cell (SOFC) diagnosis, and the challenges currently faced by AC impedance modelling and validation were identified and possible directions and approaches in addressing these challenges were suggested.
Journal ArticleDOI

Impedance spectroscopy and its use in analyzing the steady-state AC response of solid and liquid electrolytes

TL;DR: In this article, a complex least squares fitting of small-signal frequency response data at various immittance levels is presented, and a number of actual equivalent circuits used in the past for both liquid and solid electrolytes are presented and compared.
Journal ArticleDOI

Impedance spectroscopy: old problems and new developments

TL;DR: Powerful new features have been added to the author's compex nonlinear least squares (CNLS) fitting program, and the results of a Monte Carlo simulation study of bias and statistical uncertainty in CNLS fitting of equivalent circuit data are discussed.
References
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Journal ArticleDOI

Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics

TL;DR: In this paper, the locus of the dielectric constant in the complex plane was defined to be a circular arc with end points on the axis of reals and center below this axis.
Journal ArticleDOI

Non-symmetrical dielectric relaxation behaviour arising from a simple empirical decay function

TL;DR: In this article, the empirical dielectric decay function γ(t)= exp −(t/τ 0)β was transformed analytically to give the frequency dependent complex dielectrics constant if β is chosen to be 0.50 in the range log(ωτ0) > −0.5.
Journal ArticleDOI

Dielectric Relaxation in Glycerol, Propylene Glycol, and n-Propanol

TL;DR: In this article, complex dielectric constants have been measured at frequencies from below 20 c/s to 5 mc/s over the temperature range −40° to −75°C in glycerol, −45°-to −90° in propylene glycol, and −80°-140° in npropanol.
Journal ArticleDOI

Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films

TL;DR: In this paper, the small signal a-c impedance of the cell Li]LiAsF6 (0.75M) in propylene carbonatel Lip V~O3 thin film on tin oxide covered glass substrate has been measured at room temperature as a function of frequency from 5  10 -4 Hz to 5 X l0 s Hz at various open-circuit voltages.