Journal ArticleDOI
Friedel-Crafts reactions in aqueous media and their synthetic applications
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TLDR
In this paper, a review article validates the applications of water as a solvent for Friedel-Crafts-based reaction, especially the C C C bond formations, and shows that water provides mild reaction conditions as well as protecting group free synthesis along with reactivity and selectivity in organic synthesis.About:
This article is published in Journal of Molecular Liquids.The article was published on 2018-04-01. It has received 16 citations till now. The article focuses on the topics: Organic synthesis & Chemical reaction.read more
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Biogenic and eco-benign synthesis of platinum nanoparticles (Pt NPs) using plants aqueous extracts and biological derivatives: environmental, biological and catalytic applications
A. Naseer,Abid Ali,Safdar Ali,Asif Mahmood,Heri Septya Kusuma,Arif Nazir,Muhammad Yaseen,Muhammad I. Khan,Abdul Ghaffar,Mateen Abbas,Mazhar Iqbal +10 more
TL;DR: In this paper, the biogenic synthesis of noble metal-based nanomaterials (NPs) has been discussed, and the reaction conditions effect on biogenic fabrication of Pt is discussed; the structure and sizes were also compared.
Journal ArticleDOI
Chlorinated Solvents: Their Advantages, Disadvantages, and Alternatives in Organic and Medicinal Chemistry.
TL;DR: In this paper, a review explores the properties that led to widespread use of chlorinated solvents, why there is now an increasing drive to minimize usage, and what alternatives are currently available.
Journal ArticleDOI
Hydrothermal Synthesis of Zinc Doped Nickel Ferrites: Evaluation of Structural, Magnetic and Dielectric Properties
TL;DR: In this article, a series of zinc doped nickel ferrites (ZnxNi1−xFe2O4, x = 0.1, 0.2, 0 3, 0 4 and 0.5) were prepared by hydrothermal method (at 220 °C, 16 h).
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Thioesters as Acyl Donors in Biocatalytic Friedel-Crafts-type Acylation Catalyzed by Acyltransferase from Pseudomonas Protegens.
TL;DR: It is shown that the C‐acyltransferase from Pseudomonas protegens is also able to catalyze C−S bond cleavage prior to C−C bond formation, thus aliphatic and aromatic thioesters can be used as acyl donors.
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Water and fluorinated alcohol mediated/promoted tandem insertion/aerobic oxidation/bisindolylation under metal-free conditions: Easy access to bis(indolyl)methanes
TL;DR: A green tandem reaction, including insertion/aerobic oxidation/bisindolylation, starting from indoles and diazo compounds has been developed in this article, where the combination of water and fluorinated alcohol plays dual roles as solvent and promoter in this chemical transformation.
References
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Journal ArticleDOI
Organic Reactions in Aqueous Media with a Focus on Carbon−Carbon Bond Formations: A Decade Update
TL;DR: Reaction of R,â-Unsaturated Carbonyl Compounds 3127: Reaction of R-UnSaturated Carbonies 3127 7.1.6.
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Organic Synthesis “On Water”
Arani Chanda,Valery V. Fokin +1 more
TL;DR: The currently burgeoning field of organic synthesis in aqueous media encompasses a large family of reactions, and water is still not commonly used as a sole solvent for organic synthesis, at least in part because most organic compounds do not dissolve in water to a significant extent.
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Organic chemistry in water
TL;DR: Water has emerged as a versatile solvent for organic chemistry in recent years and gives completely new reactivity, including pericyclic reactions, reactions of carbanion equivalent, and reactions of carbocation equivalent.
Journal ArticleDOI
Organic reactions in aqueous media - with a focus on carbon-carbon bond formation
TL;DR: In the last decade, there has been increasing recognition that organic reactions carried out in aqueous media may offer advantages over those occurring in organic solvents as discussed by the authors, which is the essence of organic synthesis.