Journal ArticleDOI
Generation of trifluoromethylcopper from chlorodifluoroacetate
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TLDR
In the presence of fluoride ion, methyl chlorodifluoroacetate undergoes halide ion-promoted decarboxylation to give trifluoromethide which can be trapped with cuprous iodide.About:
This article is published in Journal of Fluorine Chemistry.The article was published on 1991-12-15. It has received 56 citations till now. The article focuses on the topics: Halide & Iodide.read more
Citations
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Journal ArticleDOI
Introduction of Fluorine and Fluorine-Containing Functional Groups
TL;DR: This Review gives a brief summary of conventional fluorination reactions, including those reactions that introduce fluorinated functional groups, and focuses on modern developments in the field.
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Aromatic Trifluoromethylation with Metal Complexes
TL;DR: Molecules bearing a trifluoromethyl group constitute one of the most important classes of selectively fluorinated compounds, and derivatives bearing the CF3 group on aromatic rings are particularly numerous and important.
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18F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission Tomography
TL;DR: This piece reviews all of the reactions known to date to install the (18)F substituent and other key ( 18)F-motifs of medicinal relevance onto (hetero)arenes and suggests the radiochemical space available for PET applications will expand rapidly in the near future.
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Einführung von Fluor und fluorhaltigen funktionellen Gruppen
TL;DR: The C-F-Stammbindung as mentioned in this paper is a well-known motif in modernen Fluorierungs methoden, e.g., C-C-F binding.
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Recent Developments on the Trifluoromethylation of (Hetero)Arenes
TL;DR: This Focus review gives an overview over the recent development of trifluoromethylation of (hetero)arenes in Aryl-CF(3).