Journal ArticleDOI
Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications
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This article is published in Journal of the American Chemical Society.The article was published on 1987-09-01. It has received 1217 citations till now. The article focuses on the topics: Borane & CBS catalyst.read more
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1,2-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis
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Diphenylprolinol Silyl Ethers as Efficient Organocatalysts for the Asymmetric Michael Reaction of Aldehydes and Nitroalkenes
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Atroposelective total synthesis of axially chiral biaryl natural products.
TL;DR: Gerhard Bringmann's research interests focus on the field of analytical, synthetic, and computational natural product chemistry, i.e., on axially chiral biaryls, which is characterized by a broad structural diversity.
Journal ArticleDOI
Asymmetric construction of stereogenic carbon centers featuring a trifluoromethyl group from prochiral trifluoromethylated substrates.
TL;DR: This poster presents a probabilistic analysis of the response of Na6(CO3)(SO4)(SO3) to Na2SO4 using a high-resolution X-ray diffraction analysis for the stationary phase.
Journal ArticleDOI
The ONIOM Method and Its Applications
Lung Wa Chung,W. M. C. Sameera,Romain Ramozzi,Alister J. Page,Miho Hatanaka,Galina P. Petrova,Travis V. Harris,Travis V. Harris,Xin Li,Zhuofeng Ke,Fengyi Liu,Hai Bei Li,Lina Ding,Keiji Morokuma +13 more
TL;DR: This paper presents a meta-analyses of the proton-probes of Na6(CO3)(SO4)2, Na2SO4, and Na2CO3 of the response of the H2O/O2 “spatially aggregating substance,” which has the potential to alter the structure of the molecule and provide clues to the “building blocks” of DNA.
Related Papers (5)
Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method.
E. J. Corey,Christopher J. Helal +1 more