Journal ArticleDOI
Highly stereospecific palladium-catalysed vinylation of vinylic halides under solid-liquid phase transfer conditions.
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TLDR
In this article, conjugated dienoates, dienones and dienals are obtained with high stereospecificity (⩾95%) and in high yields from the corresponding (E,E) and (Z) vinylic halides, and substrates (methyl acrylate, methyl vinyl ketone or acrolein).About:
This article is published in Tetrahedron Letters.The article was published on 1985-01-01. It has received 285 citations till now. The article focuses on the topics: Palladium(II) acetate & Methyl vinyl ketone.read more
Citations
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Ionic liquid (molten salt) phase organometallic catalysis.
TL;DR: The advent of water-soluble organometallic complexes, especially those based on sulfonated phosphorus-containing ligands, has enabled various biphasic catalytic reactions to be conducted on an industrial scale and might combine the advantages of both homogeneous and heterogeneous catalysis.
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The heck reaction as a sharpening stone of palladium catalysis.
TL;DR: s, or keywords if they used Heck-type chemistry in their syntheses, because it became one of basic tools of organic preparations, a natural way to make organic preparations.
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Direct transition metal-catalyzed functionalization of heteroaromatic compounds
TL;DR: This critical review summarizes the progress made in this field until November 2006 and describes the development of C-H activation methods for direct functionalization of heterocyclic molecules.
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Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals.
Javier Magano,Joshua R. Dunetz +1 more
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Magical power of transition metals: past, present, and future (Nobel Lecture).
TL;DR: Although I virtually never studied outside the classroom through to the ninth grade, I was quite alert and enjoyed most of the classes, with the exception of calligraphy and Japanese language, and enjoyed the after-school hours before darkness even more, at Shonan, where only the top few of my 200-plus classmates at Yamato Junior High School attended, my lifestyle was no longer satisfactory.
References
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Journal ArticleDOI
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more
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Gas-phase reactions of organic anions as studied by the flowing afterglow technique
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Organophosphinepalladium complexes as catalysts for vinylic hydrogen substitution reactions
H. A. Dieck,R. F. Heck +1 more
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Palladium-catalyzed conjugated diene synthesis from vinylic halides and olefinic compounds
Harold A. Dieck,Richard F. Heck +1 more
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An Investigation of the Tea Aroma. Part I. New volatile black tea constituents
TL;DR: A total of 68 constitutents, mainly aldehydes, ketones and esters, have been identified for the first time in a black tea aroma concentrate using coupled gas-chromatography/mass spectrometry.
Related Papers (5)
The heck reaction as a sharpening stone of palladium catalysis.
Fine Feathers Make Fine Birds: The Heck Reaction in Modern Garb†
Armin de Meijere,Frank E. Meyer +1 more
Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides
Richard F. Heck,J. P. Nolley +1 more