Journal ArticleDOI
Hydrogen Storage in Metal-Organic Frameworks
TLDR
In this paper, different methods used for the synthesis of metal organic frameworks, the relationship between structural features and hydrogen adsorption, the strategies for hydrogen uptake improvement as well as the molecular simulation.Abstract:
Recent decades have witnessed the explosive emergence of metal organic frameworks (MOFs) as functional ultrahigh surface area materials. Categorized as an intriguing class of hybrid materials, MOFs exhibit infinite crystalline lattices with inorganic vertices and molecular-scale organic linkers. Fortunately, the large internal surface areas and overall pore volumes, adjustable pore sizes, ultralow densities, and tunable framework–adsorbate interaction by ligand functionalization and metal choice, enable MOFs to be promising materials for wide applications. In particular, these remarkable properties render MOFs potential hydrogen storage materials. By virtue of their exceptionally high surface areas, unparalleled tenability and structural diversity, MOFs have become a hotspot of research within the scientific community. This paper reviews the different methods used for the synthesis of MOFs, the relationship between structural features and hydrogen adsorption, the strategies for hydrogen uptake improvement as well as the molecular simulation.read more
Citations
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Journal ArticleDOI
The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
Journal Article
Complex Hydrides for Hydrogen Storage
Yuko Nakamori,Orimo Shin-ichi +1 more
TL;DR: In this paper, the authors presented a method to detect the presence of a tumor in the human brain using EPFL-206025 data set, which was created on 2015-03-03, modified on 2017-05-12
Journal ArticleDOI
Metal-organic framework nanosheets as building blocks for molecular sieving membranes
Yuan Peng,Yuan Peng,Yanshuo Li,Yujie Ban,Yujie Ban,Hua Jin,Hua Jin,Wenmei Jiao,Wenmei Jiao,Xinlei Liu,Weishen Yang +10 more
TL;DR: The preparation of 1-nanometer-thick sheets with large lateral area and high crystallinity from layered MOFs used as building blocks for ultrathin molecular sieve membranes, which achieve hydrogen gas permeance of up to several thousand gas permeation units (GPUs) with H2/CO2 selectivity greater than 200.
Journal ArticleDOI
Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): A review
TL;DR: This review summarizes the recent literatures on the adsorptive removal of various hazardous compounds mainly from fuel, water, and air by virgin or modified MOF materials.
Journal ArticleDOI
Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions.
Zubair Hasan,Sung Hwa Jhung +1 more
TL;DR: The adsorptive purifications of contaminated water with MOFs are discussed, in order to understand possible applications of MOFs in clean water provision and plausible adsorption or interaction mechanisms and selective adsorptions are summarized.
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Journal ArticleDOI
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