Journal ArticleDOI
Ionic liquids in separations of azeotropic systems - A review
Ana B. Pereiro,João M. M. Araújo,José M. S. S. Esperança,Isabel M. Marrucho,Luís Paulo N. Rebelo +4 more
TLDR
A critical review of methods using ionic liquids (ILs) as azeotrope breakers is provided in this paper, where three separation processes were addressed: liquid-liquid extraction, extractive distillation, and supported liquid membranes.About:
This article is published in The Journal of Chemical Thermodynamics.The article was published on 2012-03-01. It has received 412 citations till now. The article focuses on the topics: Azeotropic distillation & Extractive distillation.read more
Citations
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Journal ArticleDOI
Ionic liquids: a brief history
TL;DR: In this article, a little of how interest in ionic liquids grew and developed is shown.
Journal ArticleDOI
Toxicity of Ionic Liquids: Eco(cyto)activity as Complicated, but Unavoidable Parameter for Task-Specific Optimization
TL;DR: It is shown that biological activity and cytotoxicity of ionic liquids dramatically depend on the nature of a biological system, and a careful selection of biological activity data is a must for the correct assessment of chemical technologies involving ionic liquid.
Journal ArticleDOI
Ionic liquids and deep eutectic mixtures: sustainable solvents for extraction processes
TL;DR: In this article, the applicability of ionic liquids and deep eutectic mixtures in a variety of extraction techniques, including but not limited to liquid-and solid-phase (micro) extraction, microwave-assisted extraction, ultrasound assisted extraction and pressurized liquid extraction, is discussed.
Journal ArticleDOI
Extractive distillation with ionic liquids: A review
TL;DR: A comprehensive review on the recent progress made by chemical engineers focusing on the issues of predictive thermodynamic models, structure-property relations, separation mechanisms, and process simulation and optimization is provided in this article.
Journal ArticleDOI
Deep eutectic solvents as extraction media for azeotropic mixtures
Filipe S. Oliveira,Ana B. Pereiro,Luís Paulo N. Rebelo,Isabel M. Marrucho,Isabel M. Marrucho +4 more
TL;DR: In this article, three different deep eutectic solvents, all based on choline chloride, were used for the liquid-liquid separation of an azeotropic mixture of heptane + ethanol at 25 °C.
References
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Book
CRC Handbook of Chemistry and Physics
TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Journal ArticleDOI
Applications of ionic liquids in the chemical industry
TL;DR: There have been parallel and collaborative exchanges between academic research and industrial developments since the materials were first reported in 1914, it is demonstrated.
Journal ArticleDOI
Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation
Jonathan G. Huddleston,Ann E. Visser,W. Matthew Reichert,Heather D. Willauer,Grant A. Broker,Robin D. Rogers +5 more
TL;DR: A series of hydrophilic and hydrophobic 1-alkyl-3-methylimidazolium room temperature ionic liquids (RTILs) have been prepared and characterized to determine how water content, density, viscosity, surface tension, melting point, and thermal stability are affected by changes in alkyl chain length and anion.
Journal ArticleDOI
The distillation and volatility of ionic liquids
Martyn J. Earle,José M. S. S. Esperança,Manuela A. Gilea,José N. Canongia Lopes,Luís Paulo N. Rebelo,Joseph W. Magee,Kenneth R. Seddon,Jason A. Widegren +7 more
TL;DR: It is demonstrated that some selected families of commonly used aprotic ionic liquids can be distilled at 200–300 °C and low pressure, with concomitant recovery of significant amounts of pure substance, will permit these currently excluded applications to be realized.
Book
Industrial Organic Chemistry
TL;DR: In this paper, the authors describe current industrial applications of organic chemistry and offer an excellent overview of industrial organic chemistry, covering the manufacture of the most important precursors and intermediates and their use in the development of commercial products.
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