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Low-cost ceramic membranes: A research opportunity for industrial application

TLDR
In this paper, the authors exhaustively review the raw materials, ceramic compositions and variables of the manufacturing processes used in the development of these membranes, with special emphasis on their numerous potential industrial applications.
Abstract
Obtaining low-cost ceramic membranes has attracted great interest in the scientific community in last years, as it allows to preserve the advantages of ceramic materials while significantly reduce their manufacturing costs. This type of membranes is mainly based on the use of raw materials and manufacturing processes typical of traditional ceramic materials, i.e silicate-based ceramics. This work exhaustively reviews the raw materials, ceramic compositions and variables of the manufacturing processes used in the development of these membranes, with special emphasis on their numerous potential industrial applications.

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Journal ArticleDOI

Materials and Applications for Low-Cost Ceramic Membranes.

TL;DR: This review presents recent developments in materials and processes for the fabrication of low-cost membranes from unrefined raw materials, including clays, zeolites, apatite, waste products, including fly ash and rice husk ash, and cement.
Journal ArticleDOI

Anaerobic membrane bioreactor towards biowaste biorefinery and chemical energy harvest: Recent progress, membrane fouling and future perspectives

TL;DR: In this article, a new generation integrated multistage bio-process (IMBP) constituted of solar-driven bioelectrochemical system (BES)-AnMBR, partial nitritation/anammox (PN/A), nitrate reduction via anaerobic oxidation of methane (AOM) and biological/chemical phosphorus precipitation units, with versatile capabilities in simultaneous biowastes valorization, CO2 electromethanogenesis and simultaneous biogas upgrading, in-situ fouling control, ammonia removal, dissolved methane reutilization, and phosphorus
Journal ArticleDOI

Cost and efficiency perspectives of ceramic membranes for water treatment.

TL;DR: More robust ceramic membranes with tailorable structures and functions are increasingly employed for water treatment, particularly in some harsh applications for their ultra-long service lifespan due to their high mechanical, structural, chemical and thermal stability and anti-fouling properties as mentioned in this paper .
Journal ArticleDOI

Preparation of novel porous ceramic microfiltration membranes from fly ash, kaolin and dolomite mixtures

TL;DR: In this paper, low-cost ceramic membranes were prepared by using kaolin (KA), fly ash (FA) and dolomite, and the results showed that the resulting membranes were free of defects and had homogeneous surface structure with evenly distributed pores of similar sizes.
Journal ArticleDOI

Influencing factors on the performance of tubular ceramic membrane supports prepared by extrusion

TL;DR: In this paper, a comparative and comprehensive study on the process parameters and influencing factors in the process of preparing ceramic membrane support by extrusion to obtain the support with the best performance is presented.
References
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Book

Basic Principles of Membrane Technology

Marcel Mulder
TL;DR: In this paper, the authors introduce the concept of Membrane Fouling and discuss the properties and properties of synthetic Membranes, including material properties, properties, and processes.
Book

Membrane Technology and Applications

TL;DR: Overview of membrane science and technology membrane transport theory membrane and modules concentration polarization reverse osmosis ultrafiltration microfiltration gas separation pervaporation ion exchange membrane processes - electrodialysis carrier facilitated transport medical applications of membranes other membranes processed.
Journal ArticleDOI

Pushing the limits on possibilities for large scale gas separation: which strategies?

TL;DR: The current spectrum of applications of gas separation membranes include: nitrogen enrichment, oxygen enrichment, hydrogen recovery, acid gas (CO2, H2S) removal from natural gas and dehydration of air and natural gas as discussed by the authors.
Book

Principles of Ceramics Processing

James S. Reed
TL;DR: In this article, the authors present a detailed table of contents of the Ceramics Processing and Ceramic Products (CPMP) and discuss the main components of the process. But they do not provide a detailed description of the procedure.
Book

Ceramic Membranes for Separation and Reaction

Kang Li
TL;DR: In this article, the authors present an overview of the literature on porous fiber contactors and their application in the diffusion of gases in porous fiber membranes, including the following: 1.1 Introduction. 2.2.
Related Papers (5)
Frequently Asked Questions (16)
Q1. What are the key compositional characteristics for the extrusion process?

Nature (plasticity) of the material, particle size and water content are the key compositional characteristics for the extrusion process [5,66,67]. 

This work exhaustively reviews the raw materials, ceramic compositions and variables of the manufacturing processes used in the development of these membranes, with special emphasis on their numerous potential industrial applications. 

The driving force of this research activity has been the clear possibility of lowering the cost of current ceramic membranes, based on ceramic oxides, maintaining, as far as possible, their performance. Broadly speaking, regarding the starting compositions employed, there are two main different branches: compositions based on advanced ceramics ( e. g. those containing alumina ) with potential applications in very aggressive media and compositions exclusively based on traditional ceramics with applications with lower demanding performance. Low-cost ceramic substrates can be used directly as microfiltration membranes. The potential applications of low-cost ceramic membranes cover virtually all applications of commercial ceramic membranes obtained with pure oxides. 

Dip-coating is the main deposition method for selective layers where conventional compositions are used to follow the low-cost philosophy by means of a higher intensity milling. 

Mullite-based ceramic membranes represent one of the best alternatives to alumina due to their excellent properties such as low thermal expansion and conductivity, excellent thermal shock resistance and high thermal, chemical and mechanical stability [39,40]. 

selective layers can also be applied to them, which reduce the effective pore size of the membranes and allow them to be used in other separation processes. 

Tests with synthetic aqueous solution containing microbial charge revealed good membrane selectivity with a microorganism rejection higher than 90 %.and those based on low-cost raw materials incorporating selective layersLow-cost ceramic membranes possess the characteristics of ceramic materials: chemical stability, high mechanical resistance, brittleness, thermal and electrical insulation, etc. 

Among all the available separation technologies, membrane filtration is one of the most promising methods for the separation of water-oil emulsions, due to its advantages: no chemical additives are needed to break the emulsions, it has high efficiency in the elimination of COD and the installations are compact and automated. 

The most developed industrial separation processes that make use of membrane technology are microfiltration, ultrafiltration, nanofiltration, reverse osmosis and electrodialysis. 

Other factors influencing the thickness and morphology of the resulting layer are the viscosity and density of the suspension, as well as the speed of substrate extraction. 

Some reported characteristics of the firing cycles for selective layer sintering are as follows: slow heating rate (1-4 ºC∙min-1) to avoid cracking, maximum sintering temperature lower than that of the substrate and dwell time between 1-2 hours. 

the use of low-cost ceramic membranes for the recovery of whey has a twofold advantage: increase the profits of the farmer and reduce pollution of river water. 

in recent years there has been an increase in the number of studies valuing wastes in the production of low-cost ceramic membranes, as a main ingredient with diverse functionality or as a pore forming material, depending on the nature of the waste used. 

The properties of low-cost ceramic membranes are determined by their composition (nature and proportion of raw materials and additives), the content and type of pore-forming materials and the firing cycle (sintering temperature and dwell time). 

Although research activity on low-cost membranes has been intense in recent years, due to the numerous potential applications in the industry, very few studies have attempted to correlate the microstructural characteristics of sintered substrates with their functional properties, due to the fact that the use of natural minerals (clay, kaolin, etc.) as raw materials makes it difficult to model the intricate microstructure of these membranes [1,24]. 

Very commonly, pore former materials are indispensable for the ceramic membrane to obtain the necessary pore size and porosity for the intended application.