Journal ArticleDOI
Mechanism of the ene reaction between singlet oxygen and olefins
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This article is published in Accounts of Chemical Research.The article was published on 1980-11-01. It has received 129 citations till now. The article focuses on the topics: Ene reaction & Singlet oxygen.read more
Citations
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Using Singlet Oxygen to Synthesize Natural Products and Drugs
TL;DR: This Review is intended to draw a logical link between flow and batch reactions-a combination that leads to the current state of (1)O2 in synthesis.
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Bifurcations on Potential Energy Surfaces of Organic Reactions
TL;DR: This Minireview covers recent investigations of organic reactions exhibiting reaction pathway bifurcations, which are surprisingly general and affect experimental observables such as kinetic isotope effects and product distributions.
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The nitroso ene reaction: a regioselective and stereoselective allylic nitrogen functionalization of mechanistic delight and synthetic potential
Waldemar Adam,Oliver Krebs +1 more
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Regioselectivity in the Ene Reaction of Singlet Oxygen with Alkenes
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Iron and redox cycling. Do's and don'ts.
TL;DR: The clinically utilised chelators desferrioxamine, deferiprone and deferasirox in each case render iron complexes with large negative electrode potentials, thus being effective in preventing iron redox cycling and the associated toxicity resulting from such activity.
References
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Journal ArticleDOI
Mechanism and stereoselectivity of photosensitized oxygen transfer reactions
K. Gollnick,G. O. Schenck +1 more
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The physics, chemistry, and biology, of singlet molecular oxygen*
Michael Kasha,Ahsan U. Khan +1 more
TL;DR: The physics, chemistry, and biology of singlet molecular oxygen are topics of the liveliest current research interest as mentioned in this paper, and its ready detection by a variety of methods, and its unusual chemical reactivities have made this subject one of the most rapidly developing research fields.