Journal ArticleDOI
Mechanism of thermal decomposition of n-butyl(tri-n-butylphosphine) copper(I)
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 102 citations till now. The article focuses on the topics: Thermal decomposition.read more
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Dialkylpalladium(II) Complexes. Syntheses, Characterizations, and Reactions with CO, I2, and CH3I
TL;DR: In this article, a series of dialkylpalladium(II) complexes were characterized by means of elemental analysis, IR and 1H-NMR spectra and of some decomposition reaction such as thermolysis and acidolysis.
Journal ArticleDOI
Formation and decomposition of alkyl-gold(I) complexes
A. Tamaki,Jay K. Kochi +1 more
TL;DR: In this article, the synthesis of new primary, secondary and tertiary alkyl(triphenylphosphine)gold(I) complexes is described, and a mechanism for reductive coupling to ethane is proposed.
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Organocopper reagents in dimethyl sulfide
Steven H. Bertz,Gary Dabbagh +1 more
TL;DR: Organocopper(I) reagents, RCu, are both more stable and more reactive when prepared in dimethyl sulfide instead of ether or tetrahydrofuran as discussed by the authors.
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Unimolecular Reactions of Organocuprates and Organoargentates
TL;DR: In this article, the gas-phase fragmentation reactions of the group 11 organometallates [CH3MR] were studied by density functional theory (DFT) calculations and, for those accessible in the gas phase, via collision-induced dissociation (CID) and selected deuterium labeling experiments.