Journal ArticleDOI
Mechanism of thermal decomposition of n-butyl(tri-n-butylphosphine) copper(I)
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 102 citations till now. The article focuses on the topics: Thermal decomposition.read more
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Elimination and catalytic decomposition of dialkylmanganese species
M. Tamura,Jay K. Kochi +1 more
TL;DR: In this article, the stochastic properties of dialkylmanganese species were examined and the decomposition process was shown to proceed principally by α,β-elimination of an hydrido, and the resulting mixture was catalyzed in a remarkable way by reduced Fe, Co, Ni, Ag and Pd.
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Copper-catalyzed conjugate additions of organozirconocenes. Synthetic and mechanistic studies.
TL;DR: In this paper, a mechanism involving enone complexation by the Lewis-acidic zirconocene followed by inner-sphere transfer of the alkyl substituent to chelated Cu(l) is proposed.
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Observations on the thermal decomposition of some uranium(IV) tetraalkyls
Tobin J. Marks,Afif M. Seyam +1 more
TL;DR: The thermally unstable products of the reactions 4 RLi + UCl 4 (R = various alkyl groups), presumed to be uranium tetraalkyls, decompose readily at room temperature in ethereal or hydrocarbon solvents as discussed by the authors.
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Disproportionation and coupling reactions of alkyl iodides on a Au(111) surface
TL;DR: The chemistry of linear (C2-C4) alkyl iodides on a Au(111) surface has been studied by temperature programmed reaction (TPR) spectroscopy, surface work function change (ΔΦ) measurements, and by low energy electron diffraction (LEED).