Journal ArticleDOI
Mechanism of thermal decomposition of n-butyl(tri-n-butylphosphine) copper(I)
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 102 citations till now. The article focuses on the topics: Thermal decomposition.read more
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Preparation and crystallographic characterization of a hexameric triphenylphosphinecopper hydride cluster
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Amino acid synthesis via ring opening of N-sulphonyl aziridine-2-carboxylate esters with organometallic reagents
TL;DR: In this article, the nucleophilic ring opening of optically active N-sulphonyl aziridine-2-carboxylate esters with organometallic reagents has been investigated as a method of preparation of amino acids.
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Reactifs de grignard vinyliques γ fonctionnels: I. Reactivite des organomagnesiens vis-a-vis d'alcools α acetyleniques en presence d'halogenures cuivreux☆
TL;DR: In this paper, primary α-acetylenic alcohols undergo regio-and stereo-specific additiions of Grignard reagents in the presence of cuprous halides.
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The Reactions of Grignard Reagents with Transition Metal Halides: Coupling, Disproportionation, and Exchange with Olefins
M. Tamura,Jay K. Kochi +1 more
TL;DR: The reactions of transition metal halides (Mn, Fe, Co, Ni, Pd, Cu, and Ag) with the low-molecular-weight alkyl Grignard reagents in tetrahydrofuran and diethyl ether, especially in the presence of styrene, were investigated in this paper.
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Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins.
TL;DR: Kinetic and spectroscopic studies showed that the turnover-limiting step is regeneration of the CuH catalyst by reaction with a silane, with a phosphine-ligated copper(I) benzoate as the catalyst resting state, consistent with a monomeric active catalyst.