Journal ArticleDOI
Mechanism of thermal decomposition of n-butyl(tri-n-butylphosphine) copper(I)
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 102 citations till now. The article focuses on the topics: Thermal decomposition.read more
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Evidence for the intermediacy of π-allylic metal complexes in the reaction of allylic halides with grignard reagent in the presence of transition metal halides
Y. Ohbe,Makoto Takagi,T. Matsuda +2 more
TL;DR: In this article, the reactions of allyl bromide and crotyl chloride with Grignard reagent catalyzed by π-allyl and Crotyl metal complexes of nickel, cobalt, and iron have been examined.
Journal ArticleDOI
Effect of nitrogen flow rate on TaN diffusion barrier layer deposited between a Cu layer and a Si-based substrate
TL;DR: In this paper, a TaN x layer was used as a barrier between Cu and a p-type Si-based substrate, and various N 2 flow rates were used during deposition along with a fixed Radio Frequency (RF) power and a fixed Ar-sputtering flow rate.
Reference EntryDOI
Substitution Reactions Using Organocopper Reagents
TL;DR: In this paper, the authors consider a number of substitution reactions using organocopper reagents, to scope, limitations, and synthetic utility of these reactions, and to optimal experimental considerations for their application.
Journal ArticleDOI
Neue Reagenzien, IV. CC-Verknüpfungen durch Organo-Kupferverbindungen mit stabilisierenden elementorganischen Gruppen
Thomas Kauffmann,Rolf Joußen +1 more
TL;DR: Organo-copper compounds with stabilizing elementorganic groups are surprisingly stable in ether or THF and react with organic iodides to give substitution products with a new CC-bond as mentioned in this paper.
Journal ArticleDOI
Synthesis and thermal decomposition of methyl(tri-t-butylphosphine)copper
TL;DR: In this article, a tri-t-butylphosphine-copper complex was obtained from the reaction of Cu(acac) 2 with Me 2 AlOEt in the presence of tri-to-Butylphophosphine in diethyl ether.