Journal ArticleDOI
Mechanism of thermal decomposition of n-butyl(tri-n-butylphosphine) copper(I)
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 102 citations till now. The article focuses on the topics: Thermal decomposition.read more
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Journal ArticleDOI
Preparation of new alkychromium complexes RCrCl2(BASE)n (R = CH3, C2H5) and effects of the base on their thermal stability
TL;DR: In this article, the thermal stability of the isolated alkychromium complexes is discussed in terms of the electronic and steric effects of the coordinated bases and of ease of abstraction of hydrogen from the bases by the alkyl groups.
Journal ArticleDOI
Reactions of organolithium compounds with cobaltous chloride
Donald B. Denney,William Davis +1 more
TL;DR: The reactions of cis -and trans -2-lithio-2-butenes with cobaltous ion yield 3,4-dimethyl-2,4hexadienes with essentially complete retention of stereochemistry as mentioned in this paper.
Journal ArticleDOI
Direct evidence for the β-hydride elimination mechanism in the decomposition of triethylgallium on GaAs(100)
K. C. Wong,M. T. McEllistrem,Brian G. McBurnett,Robert D. Culp,Alan H. Cowley,John G. Ekerdt +5 more
TL;DR: In this article, the surface ethyl group formed by dissociative adsorption of triethylgallium (TEGa) on GaAs(100) was investigated using temperature programmed desorption.
Book ChapterDOI
New Properties of Reagents by Complexation of Carbanions on Transition-Metals: Which Metal is in Each Case the Most Favorable One?
TL;DR: The transmetallation of carbanionid derivatives of Li, Mg or Zn by treating with transition-metal halides is the most important method for the preparation of transition metal alkyls as mentioned in this paper.