Journal ArticleDOI
Reaction of lithium dialkyl- and diarylcuprates with organic halides
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This article is published in Journal of the American Chemical Society.The article was published on 1969-08-01. It has received 256 citations till now. The article focuses on the topics: Lithium & Halide.read more
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Aerobic Copper-Catalyzed Organic Reactions
TL;DR: The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and CuIII oxidation states allowing it to act through one-electron or two-Electron processes, which feature confer a remarkably broad range of activities allowing copper to catalyze the oxidation and oxidative union of many substrates.
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Mechanisms of Nucleophilic Organocopper(I) Reactions
Naohiko Yoshikai,Eiichi Nakamura +1 more
Journal ArticleDOI
The mechanism of the modified Ullmann reaction
TL;DR: A recent DFT study by Houk, Buchwald and co-workers shows that the modified Ullmann reaction between aryl iodide and amines or primary alcohols proceeds either via an SET or an IAT mechanism, suggesting a Cu(I)/Cu(III) type mechanism for the amidation (Goldberg) reaction.
Journal ArticleDOI
Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions.
TL;DR: In this article, the authors investigated ligand-directed selectivities in Ullmann-type coupling reactions of methanol and methylamine with iodobenzene by β-diketone-and 1,10-phenanthroline-ligated CuI complexes.
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