Journal ArticleDOI
Mesityl-phenolato-vanadium(III)-Komplexe: Synthese, Struktur und Verhalten
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This article is published in Zeitschrift für anorganische und allgemeine Chemie.The article was published on 2002-01-01. It has received 21 citations till now.read more
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Trigonal Bipyramidal or Square Pyramidal Coordination Geometry? Investigating the Most Potent Geometry for Vanadium Phosphatase Inhibitors
TL;DR: In this article, the authors analyzed the five-coordinate geometry of VO4X coordination spheres with regard to their structure from the point of view of square pyramidal or trigonal bipyramidal geometries.
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Lithium phenolates solvated by tetrahydrofuran and 1,2-dimethoxyethane: structure determination using the method of continuous variation.
Timothy S. De Vries,Anandarup Goswami,Lara R. Liou,Jocelyn M. Gruver,Emily Jayne,David B. Collum +5 more
TL;DR: The method of continuous variation in conjunction with Li NMR spectroscopy was used to characterize lithium phenolates solvated by tetrahydrofuran and 1,2-dimethoxyethane, and the refinement of protocols for characterizing O-lithiated species are discussed.
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Organic heterobimetallic complexes of the alkaline earth metals (Ae = Ca, Sr, Ba) with tetrahedral metallate anions of three-valent metals (M = B, Al, Ga, and V)
TL;DR: In this paper, the average structural parameters of the boranates [Ca(thf)6][BPh4]2 (1), the alanates [Li(thfa)2(tmeda)][AlPh3(tmp)] (3), [(thfa 2K(N-carbazolyl)2AlMes2] (4), and [Sr(thfb)7][Alph4] 2 (5), of the gallate [Ca (dme)4][GaEt3(N)-carbazyl
Journal ArticleDOI
Linear and Nonlinear Two-Coordinate Vanadium Complexes: Synthesis, Characterization, and Magnetic Properties of V(II) Amides
Jessica N. Boynton,Jing-Dong Guo,James C. Fettinger,Christopher E. Melton,Shigeru Nagase,Philip P. Power +5 more
TL;DR: The synthesis and characterization of the first stable two-coordinate vanadium complexes are described and magnetometry studies showed that the major absorptions in their UV-vis spectra were due to ligand to metal charge transfer transitions.
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3d early transition metal complexes supported by a new sterically demanding aryloxide ligand
TL;DR: Single-crystal X-ray diffraction studies of 1, 2, and the 3d metal complexes 5-8 clearly show the steric demand of the bulky ligand, whereas in transition metal complexes the authors do not observe the formation of mononuclear tris-aryloxide complexes.