Journal ArticleDOI
Metal complex catalysis in the synthesis of quinolines
TLDR
In this paper, a review of published data about the synthesis of quinolines by the reactions of anilines with aldehydes, alkenes, alkynes, alkyl amines, alcohols, 1,2-diols, and 1,3-dioxiols using metal complex catalysts based on Ru, Pt, Rh, Pd, Ir, In, Mo, Co, Bi, Ga, Sc, Hf, Ti, Fe, Ni, Au, Ag, Cu, and Ln.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 2014-10-01. It has received 55 citations till now. The article focuses on the topics: Catalysis & Alkyl.read more
Citations
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Green recipes to quinoline: A review
Lalit Mohan Nainwal,Sharba Tasneem,Wasim Akhtar,Garima Verma,Mohammed Faraz Khan,Suhel Parvez,Mohammad Shaquiquzzaman,Mymoona Akhter,Mohammad Mumtaz Alam +8 more
TL;DR: This review provides a concise overview of new dimensions of green chemistry approaches in designing quinoline scaffold that would encourage the researchers towards green chemistry as well as future application of these greener, non-toxic, environment friendly methods.
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Dehydrogenative Synthesis of Quinolines, 2-Aminoquinolines, and Quinazolines Using Singlet Diradical Ni(II)-Catalysts
Gargi Chakraborty,Rina Sikari,Siuli Das,Rakesh Mondal,Suman Sinha,Seemika Banerjee,Nanda D. Paul +6 more
TL;DR: Insight was carried out into the reaction mechanism which shows that the nickel and the coordinated diamine ligands participate in a synergistic way during the dehydrogenation of alcohols.
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Synthesis of 2-Alkenylquinoline by Reductive Olefination of Quinoline N-Oxide under Metal-Free Conditions.
TL;DR: A possible mechanism is proposed that involves a sequential 1,3-dipolar cycloaddition and acid-assisted ring opening followed by a dehydration process, which could be performed with quinoline as starting material via a one-pot, two-step process.
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Recent developments in the preparation of N-heterocycles using Pd-catalysed C–H activation
TL;DR: A recent review summarizes the recent developments in this area which employs Pd 0 -Pd IV as versatile catalyst precursors to the syntheses of N-heterocycles.
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Synthesis of Quinolines through Three-Component Cascade Annulation of Aryl Diazonium Salts, Nitriles, and Alkynes
TL;DR: An efficient and rapid synthesis of multiply substituted quinolines is described, enabled by a three-component cascade annulation of readily available aryl diazonium salts, nitriles, and alkynes.
References
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Recent Progress in the Synthesis of Quinolines
TL;DR: In this article, two general synthetic routes based on the utilization of mono-substituted or ortho-subtituted anilines are discussed and their major methods and modifications are analyzed.
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Intramolecular aromatic substitution in transition metal complexes
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The ruthenium catalyzed N-alkylation and N-heterocyclization of aniline using alcohols and aldehydes
TL;DR: Aniline reacts with saturated and 2,3-unsaturated alcohols in the presence of ruthenium catalyst at 180°C to give N-alkylanilines and 2-3-alkylquinolines in good yields as discussed by the authors.
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Ruthenium-catalyzed N-alkylation and N-benzylation of aminoarenes with alcohols
TL;DR: In this article, a cycle catalytique was proposed to meet en jeu une attaque nucleophile de l'aminoarene sur un aldehyde intermediaire.