Journal ArticleDOI
Metal-Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications.
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TLDR
In this article, the recent advances in the design, synthesis, and functional applications of metal-organic frameworks (MOFs) based hierarchically porous materials are summarized, and a comparison of HP-MOFs with traditional porous materials (e.g., zeolite, porous silica, carbons, metal oxides, and polymers) are also indicated.Abstract:
Metal-organic frameworks (MOFs) have been widely recognized as one of the most fascinating classes of materials from science and engineering perspectives, benefiting from their high porosity and well-defined and tailored structures and components at the atomic level. Although their intrinsic micropores endow size-selective capability and high surface area, etc., the narrow pores limit their applications toward diffusion-control and large-size species involved processes. In recent years, the construction of hierarchically porous MOFs (HP-MOFs), MOF-based hierarchically porous composites, and MOF-based hierarchically porous derivatives has captured widespread interest to extend the applications of conventional MOF-based materials. In this Review, the recent advances in the design, synthesis, and functional applications of MOF-based hierarchically porous materials are summarized. Their structural characters toward various applications, including catalysis, gas storage and separation, air filtration, sewage treatment, sensing and energy storage, have been demonstrated with typical reports. The comparison of HP-MOFs with traditional porous materials (e.g., zeolite, porous silica, carbons, metal oxides, and polymers), subsisting challenges, as well as future directions in this research field, are also indicated.read more
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Journal ArticleDOI
Metal-organic framework nanocrystal-derived hollow porous materials: Synthetic strategies and emerging applications
Xiaolu Liu,Gaurav Verma,Zhong-Ying Chen,Baowei Hu,Qi-Fei Huang,Hui Yang,Shengqian Ma,Xiangke Wang +7 more
TL;DR: A comprehensive overview of the synthetic strategies and emerging applications of hollow porous materials derived from MOF-based templates and/or precursors is given in this article , where a perspective on the research challenges and future opportunities and prospects for MOF derived hollow materials is provided.
Journal ArticleDOI
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization.
Jian Liu,Timothy A. Goetjen,Qining Wang,Julia G. Knapp,Megan C. Wasson,Ying-Chao Yang,Zoha H. Syed,Massimiliano Delferro,Justin M. Notestein,Omar K. Farha,Joseph T. Hupp +10 more
TL;DR: This review focuses on how porous, catalyst-containing MOFs capitalize on molecular-scale confinement, containment, isolation, environment modulation, energy delivery, and mobility to accomplish desired chemical transformations with potentially superior selectivity or other efficacy, especially in comparison to catalysts in homogeneous solution environments.
Journal ArticleDOI
Construction and application of base-stable MOFs: a critical review.
TL;DR: In this article , a review of the development of base-stable metal-organic frameworks (MOFs) can be found, where the key factors that can determine the robustness of MOFs under basic conditions are analyzed.
Journal ArticleDOI
Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis
TL;DR: The 2D nanosheets of metal-organic frameworks (MOFs) have recently emerged as a promising material that makes them valuable in widespread electrocatalytic fields due to their atomic-level thickness, abundant active sites, and large surface area as discussed by the authors .
Journal ArticleDOI
Ni single-atom sites supported on carbon aerogel for highly efficient electroreduction of carbon dioxide with industrial current densities
TL;DR: In this article , N-doped carbon aerogels supporting Ni single-atom sites (Ni-NCA-X, X = 10, 20) were fabricated by pyrolyzing Ni/Zn bimetallic zeolitic imidazolate framework (Ni/ZN-ZIF-8)/carboxymethylcellulose composite gels.
References
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Journal ArticleDOI
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Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
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Metal–Organic Framework Materials as Chemical Sensors
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Carbon Dioxide Capture in Metal–Organic Frameworks
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