A ZIF-8 thin film-based Fabry-Pérot device has been fabricated as a selective sensor for chemical vapors and gases as well as a series of ZIF -8 thin films grown on silicon substrates.
Abstract:
A ZIF-8 thin film-based Fabry−Perot device has been fabricated as a selective sensor for chemical vapors and gases. The preparation of the ZIF-8 thin film and a series of ZIF-8 thin films of various thicknesses grown on silicon substrates are presented.
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
TL;DR: This critical review discusses the origins of MOF luminosity, which include the linker, the coordinated metal ions, antenna effects, excimer and exciplex formation, and guest molecules.
TL;DR: This comprehensive review summarizes the topical developments in the field of luminescent MOF and MOF-based photonic crystals/thin film sensory materials.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
TL;DR: This work has shown that highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
Q1. What contributions have the authors mentioned in the paper "Metal-organic frameworks as sensors: a zif-8 based fabry-pérot device as a selective sensor for chemical vapors and gases" ?
Among the potential applications for which proof-of-concept reports have proliferated are gas storage, chemical catalysis, and smallmolecule separations. The challenge is signal transduction: the cavities of MOFs are generally too small to tailor with reporter molecules, i. e. moieties that can readily signal analytebinding events via changes in color, redox potential, or other properties. Here the authors describe an alternative approach that circumvents the need for molecular-level reporters and instead relies upon a readout of changes in a macroscopic property of the sensing material, the refractive index.
Q2. What are the advantages of the method?
Virtues of this method include gentle reaction conditions (room temperature), rapid growth rate (∼100 nm/30 min), good control over thickness (∼ 100 nm/cycle), no special requirements for surface modification of substrates, and ease of removal of solvent (methanol).
Q3. How much is the volume fraction of analyte in the framework?
From the magnitudes of the shifts in the interference fringes, the authors calculated that the volume fraction of analyte in the framework is ∼0.13 for pure propane at 1 atm.
Q4. How much ethanol is detected in water?
For 1 nm resolution, the estimated detection limit for ethanol in water is ca. 0.3 vol %, corresponding to an ethanol vapor concentration of ca. 100 ppm.
Q5. What is the ethanol concentration in the framework?
Exposure to the vapor above ethanol/ water mixtures of various ethanol contents gives rise to ethanolconcentration-dependent responses, with the sensor response saturating at ca. 40% ethanol (Figure 4B).
Q6. What is the void fraction of analyte in the framework?
The authors have taken advantage of this observation to calculate the volume fraction of analyte in the framework: 0.25 for pure ethanol, which agrees reasonably well with the void volume fraction (0.20) indicated by single-crystal X-ray structural measurements.
Q7. What is the spectral properties of the ZIF-8?
Fabry-Pérot fringes for transmission of visible light through a ca. 1000 nm thick film (10-cycle growth) of ZIF-8 on glass were monitored to demonstrate the sensing properties.