Journal ArticleDOI
Modification of poly(ethylene 2,5-furandicarboxylate) with 1,4-cyclohexanedimethylene: Influence of composition on mechanical and barrier properties
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TLDR
In this article, a series of poly(ethylene- co -1,4-cyclohexanedimethylene 2,5-furandicarboxylate)s (PECFs) with different compositions were synthesized from 2-5-Furandic-arboxylic acid (FDCA), 1-4-Cyclohexane (CHDM) and ethylene glycol (EG), their chemical structures, composition and sequence distribution were determined by FT-IR, 1 H NMR and 13 C NMR.About:
This article is published in Polymer.The article was published on 2016-10-26. It has received 126 citations till now. The article focuses on the topics: Ethylene glycol.read more
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Bio-based polyesters: Recent progress and future prospects
TL;DR: A review on the recent advances in the field of bio-based polyesters is presented in this paper, where the authors present the common challenges faced by bio-polyester elastomers and the prospects for future development.
Journal ArticleDOI
Tuning the Properties of Furandicarboxylic Acid-Based Polyesters with Copolymerization: A Review.
Zoi Terzopoulou,Zoi Terzopoulou,Lazaros Papadopoulos,Alexandra Zamboulis,Dimitrios G. Papageorgiou,George Z. Papageorgiou,Dimitrios N. Bikiaris +6 more
TL;DR: This present review aims to summarize the trends in the synthesis of FDCA-based copolymers and to investigate the effectiveness of this approach in transforming them to a more versatile class of materials that could potentially be appropriate for a number of high-end and conventional applications.
Journal ArticleDOI
A Perspective on PEF Synthesis, Properties, and End-Life.
Katja Loos,Ruoyu Zhang,Inês C. Pereira,Beatriz Agostinho,Han Hu,Dina Maniar,Nicolas Sbirrazzuoli,Armando J. D. Silvestre,Nathanael Guigo,Andreia F. Sousa +9 more
TL;DR: This critical review considers the extensive research and development dedicated, in the last years, to a single polymer, the poly(ethylene 2,5-furandicarboxylate), usually simply referred to as PEF, for the first time synthesis, properties, and end-life targeting—a more sustainable PEF—are critically reviewed.
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Advances in polymer precursors and bio‐based polymers synthesized from 5‐hydroxymethylfurfural
Daihui Zhang,Marie-Josée Dumont +1 more
TL;DR: A review of 5-hydroxymethylfurfural (HMF) derivatives can be found in this paper, where the authors discuss the current research studies related to the derivatives of HMF, alongside with the synthesis and characterization of (co-) polymers derived from HMF and its derivatives.
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Biobased Poly(ethylene 2,5-furancoate): No Longer an Alternative, but an Irreplaceable Polyester in the Polymer Industry
TL;DR: In this article, the synthesis, modification, and functionalization of polyesters derived from 2,5-furandicarboxylic acid (2-5-FDCA) have attracted widespread attention.
References
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Technology development for the production of biobased products from biorefinery carbohydrates—the US Department of Energy’s “Top 10” revisited
TL;DR: An updated evaluation of potential target structures using similar selection methodology, and an overview of the technology developments that led to the inclusion of a given compound are presented.
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Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources
Robert-Jan van Putten,Jan C. van der Waal,Ed de Jong,C. B. Rasrendra,Hero J. Heeres,Johannes G. de Vries +5 more
TL;DR: Renewable Resources Robert-Jan van Putten,†,‡ Jan C. van der Waal,† Ed de Jong,*,† Carolus B. Rasrendra,*,⊥ Hero J. Heeres,*,‡ and Johannes G. de Vries.
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Conversion of biomass to selected chemical products
TL;DR: This critical review provides a survey illustrated by recent references of different strategies to achieve a sustainable conversion of biomass to bioproducts to examine critically the green character of conversion processes.
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Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels
TL;DR: A strategy by which aqueous solutions of γ-valerolactone (GVL), produced from biomass-derived carbohydrates, can be converted to liquid alkenes in the molecular weight range appropriate for transportation fuels by an integrated catalytic system that does not require an external source of hydrogen.
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Polyhydroxyalkanoates: an overview.
TL;DR: Structural studies will further improve the understanding of the mechanism of action of these enzymes and aid in improving and selecting better candidates for increased production of poly(3-hydroxybutyrate) (PHB) production.