Journal ArticleDOI
Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3
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TLDR
In this article, an X-ray structural study of MoO(OC2H4OMe) showed that its crystals are constructed of monomeric molecules with both methoxyethoxide groups forming chelate rings around the molybdenum atoms.About:
This article is published in Mendeleev Communications.The article was published on 1991-01-01. It has received 8 citations till now. The article focuses on the topics: Molybdenum & Molecule.read more
Citations
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Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand
Ari Lehtonen,Vadim G. Kessler +1 more
TL;DR: In this paper, two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H3Lig) were added to the solution of MoO2(acac)2 in MeOH results in the formation of anionic complex, which precipitates as LigH4[MoO2Lig], a yellow crystalline solid.
Journal ArticleDOI
Synthesis, crystal and molecular structure of a new heterometallic oxo-2-methoxyethoxide, BaMo2O5(OC2H4OMe)4(HOC2H4OMe)
Vadim G. Kessler,Nataliya Ya. Turova,Andrei N. Panov,Zoya A. Starikova,Alexandr I. Yanovsky,Yuri T. Struchkov,David Benlian +6 more
TL;DR: The colorless needle-shaped crystals of a new heterometallic 2-methoxyethoxide, BaMo2O5(OC2H4OMe)4(HOC 2H4 OMe) (1), have been obtained by the saturation of barium 2methoxideethoxide solution in 2mETHoxyethanol with the crystalline MoO2(OC4O5)2 as mentioned in this paper.
References
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Journal ArticleDOI
Crystal and Molecular Structure of Titanium (IV) Ethoxide
TL;DR: In this article, it was shown that the trimeric titanium (IV) ethoxide is a tetramer in the solid, and hence that this long-awaited X-ray analysis of a titanium(IV) alkoxide not only fails to confirm one of the proposed structures, but also makes unreasonable the assumption, implicit in much of the recent discussions, that the species in solution are identical with those precipitated from solution.
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The crystal and molecular structure of titanium tetramethoxide
D. A. Wright,D. A. Williams +1 more
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Soluble and volatile alkoxides of bismuth. The first structurally characterized bismuth trialkoxide: [Bi(.mu.-.eta.1-OCH2CH2OMe)2(.eta.1-OCH2OMe)].infin.
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Isolation and structural characterization of the copper-barium-alkoxide cluster Ba2Cu2(OR)4(acac)4.2HOR (R = CH2CH2OCH3) from precursor solutions to yttrium barium copper oxide (YBa2Cu3O7) thin films
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Röntgenographische, NMR- und massenspektrometrische Untersuchungen der tert.-Butylate des Kaliums, Rubidiums und Cäsiums†
TL;DR: The tert.-Butylate (CH3)3COM (M K, Rb, Cs) kristallisieren nach rontgenographischen Untersuchungen der Kristallpulver kubisch-primitiv with den Gitterkonstanten a = 8.475A (K), 8.610A (Rb) and 8.902A (Cs) and vier Formeleinheiten je Elementarzelle as mentioned in this paper.