Journal ArticleDOI
Multinuclear olefin polymerization catalysts
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This article is published in Chemical Reviews.The article was published on 2011-02-17. It has received 494 citations till now. The article focuses on the topics: Polymerization & Post-metallocene catalyst.read more
Citations
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Multimetallic catalysis based on heterometallic complexes and clusters.
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From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites
TL;DR: All-Polyolefin Composites Markus Stürzel,† Shahram Mihan,‡ and Rolf Mülhaupt*,†,§ †Freiburg Materials Research Center and Institute for Macromolecular Chemistry.
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Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning
TL;DR: Recently, some alternative design strategies have emerged that afforded new classes of olefin polymerization catalysts as mentioned in this paper, and they enable novel reactivity patterns they enable, which is a major driving force in polyolefin studies.
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Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization
TL;DR: In this paper, the chain walking polymerization mechanism is discussed followed by its implications in olefin polymerization and copolymerization with polar functionalized comonomers, and some recent developments and perspectives on very fast and very slow chain walking catalysts are discussed.
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Post-metallocenes in the industrial production of polyolefins.
TL;DR: This Review gives a comprehensive overview of post-metallocene polymerization catalysts that have been put into practice and the decisive properties for this success of a given catalyst structure are delineated.
References
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Journal ArticleDOI
The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
Tina M. Trnka,Robert H. Grubbs +1 more
TL;DR: The discussion includes an analysis of trends in catalyst activity, a description of catalysts coordinated with N-heterocyclic carbene ligands, and an overview of ongoing work to improve the activity, stability, and selectivity of this family of L2X2Ru=CHR complexes.
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Late-metal catalysts for ethylene homo- and copolymerization.
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Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
TL;DR: In contrast to heterogeneous Ziegler-Natta catalysts, homogeneous metallocene-based catalysts as discussed by the authors allow efficient control of regio-and stereoregularities, molecular weights and molecular weight distributions, and comonomer incorporation.
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New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins
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Advances in non-metallocene olefin polymerization catalysis.
TL;DR: The graph below shows the progression of monoanionic and non-monoanionic ligands through the history of synthesis, as well as some of the properties that have been identified since the discovery of R-Diimine.