Journal ArticleDOI
New interpretations of XPS spectra of nickel metal and oxides
Andrew P. Grosvenor,Mark C. Biesinger,Roger St. C. Smart,Roger St. C. Smart,N. Stewart McIntyre +4 more
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TLDR
In this paper, a scheme for fitting the Ni 2p spectra using multiplet envelopes is proposed, based on charge transfer assignments of the main peak at 854.6 eV and the broad satellite centred at around 861 eV to the cd 9 L and the unscreened cd 8 final state configurations, respectively.About:
This article is published in Surface Science.The article was published on 2006-05-01. It has received 1589 citations till now. The article focuses on the topics: Multiplet & Spectral line.read more
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Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and Zn
TL;DR: Biesinger et al. as mentioned in this paper proposed a more consistent and effective approach to curve fitting based on a combination of standard spectra from quality reference samples, a survey of appropriate literature databases and/or a compilation of literature references and specific literature references where fitting procedures are available.
Journal ArticleDOI
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems
Mark C. Biesinger,Mark C. Biesinger,B.P. Payne,Leo W. M. Lau,Andrea R. Gerson,Roger St. C. Smart +5 more
TL;DR: In this paper, an approach based on standard spectra from quality reference samples (Ni, NiO, Ni(OH)2, NiOOH), subtraction of these spectra, and data analysis that integrates information from the Ni 2p spectrum and the O 1s spectra is demonstrated.
Journal ArticleDOI
Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting.
Hanfeng Liang,Appala Naidu Gandi,Dalaver H. Anjum,Xianbin Wang,Udo Schwingenschlögl,Husam N. Alshareef +5 more
TL;DR: A novel PH3 plasma-assisted approach to convert NiCo hydroxides into ternary NiCoP that shows superior catalytic activity toward the hydrogen evolution reaction (HER) with a low overpotential and is among the most efficient earth-abundant catalysts for water splitting.
Journal ArticleDOI
Advanced analysis of copper X-ray photoelectron spectra
TL;DR: In this article, the authors extend and extend previously published X-ray photoelectron spectroscopy curve-fitting and data analysis procedures for a wide range of copper containing species.
Journal ArticleDOI
A nickel iron diselenide-derived efficient oxygen-evolution catalyst
Xiang Xu,Fang Song,Xile Hu +2 more
TL;DR: In this paper, a representative selenide catalyst is entirely converted into nickel hydroxide under oxygen-evolution conditions, showing that metal selenides are unstable during oxygen evolution, and the in situ generated metal oxides are responsible for their activity.
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Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds
TL;DR: In this paper, the authors investigated the usefulness of calculated multiplet peaks to fit high-resolution iron 2p3/2 spectra from high-spin compounds. And they found that the multiplets were found to fit most spectra well, particularly when contributions attributed to surface peaks and shake-up satellites were included.