Journal ArticleDOI
Organocatalytic Asymmetric Mannich Reactions: New Methodology, Catalyst Design, and Synthetic Applications
Amal Ting,Scott E. Schaus +1 more
TLDR
In this paper, the authors present the methodology and synthetic advantages achieved so far in the asymmetric Mannich reaction, and present a Microreview of the recent contributions to this process.About:
This article is published in European Journal of Organic Chemistry.The article was published on 2007-12-01. It has received 385 citations till now. The article focuses on the topics: Mannich reaction & Organocatalysis.read more
Citations
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Journal ArticleDOI
Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates
Journal ArticleDOI
Asymmetric Organocatalysis: From Infancy to Adolescence
TL;DR: This Review deals with selected studies reported in 2006 and the first half of 2007, and is intended to highlight four main aspects that may be taken as testimony of the present status and prospective of organocatalysis.
Journal ArticleDOI
Asymmetric aminocatalysis--gold rush in organic chemistry.
TL;DR: This Review describes this "Asymmetric Aminocatalysis Gold Rush" and charts the milestones in its development.
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Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update
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Asymmetric catalysis with bifunctional cinchona alkaloid-based urea and thiourea organocatalysts.
TL;DR: Cinchona alkaloid derivatives modified to include a (thio)urea component have emerged in the last three years as readily accessible, robust and tunable bifunctional organocatalysts for a range of synthetically useful transformations.
References
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Journal ArticleDOI
Ionic Liquids-New "Solutions" for Transition Metal Catalysis.
Peter Wasserscheid,Wilhelm Keim +1 more
TL;DR: There are indications that switching from a normal organic solvent to an ionic liquid can lead to novel and unusual chemical reactivity, which opens up a wide field for future investigations into this new class of solvents in catalytic applications.
Journal ArticleDOI
Merck molecular force field. I. Basis, form, scope, parameterization, and performance of MMFF94
TL;DR: The first published version of the Merck molecular force field (MMFF) is MMFF94 as mentioned in this paper, which is based on the OPLS force field and has been applied to condensed-phase processes.
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Microwave assisted organic synthesis-a review
Journal ArticleDOI
Catalytic reactions in ionic liquids
TL;DR: The use of ionic liquids as novel reaction media may offer a convenient solution to both the solvent emission and the catalyst recycling problem, as well as in supercritical carbon dioxide.