Journal ArticleDOI
Oxidative carbonylation reactions: organometallic compounds (R-M) or hydrocarbons (R-H) as nucleophiles.
Qiang Liu,Hua Zhang,Aiwen Lei +2 more
TLDR
This Minireview summarizes this novel type of oxidative carbonylation reaction, where organometallic reagents and hydrocarbons were directly employed as nucleophiles to construct a C-C bond in oxidative Carbonylation reactions.Abstract:
Oxidative carbonylation reactions have attracted broad interest from both academia and industry in recent years. Enormous efforts have gone into the syntheses of carbonate and urea derivatives through the oxidative carbonylation of alcohols and amines. Very recently, organometallic reagents (RM) and hydrocarbons(RH) were directly employed as nucleophiles to construct a CC bond in oxidative carbonylation reactions. This Minireview summarizes this novel type of oxidative carbonylation reaction.read more
Citations
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Beyond directing groups: transition-metal-catalyzed C-H activation of simple arenes.
TL;DR: In this review, recent advances in the emerging field of non-chelate-assisted C-H activation are discussed, highlighting some of the most intriguing and inspiring examples of induction of reactivity and selectivity.
Journal ArticleDOI
Homogeneously Catalyzed Electroreduction of Carbon Dioxide-Methods, Mechanisms, and Catalysts
TL;DR: The developments of the last three decades in electrocatalytic CO2 reduction with homogeneous catalysts are reviewed and important catalyst families are discussed in detail with regard to mechanistic aspects, and recent advances in the field are highlighted.
Journal ArticleDOI
Chemicals from Alkynes with Palladium Catalysts
Rafael Chinchilla,Carmen Nájera +1 more
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Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds
Lei Yang,Hanmin Huang +1 more
Journal ArticleDOI
Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds
TL;DR: The transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized π bonds has emerged as a particularly efficient and powerful approach for the construction of an incredibly diverse array of heteroatom-substituted products.
References
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Journal ArticleDOI
Palladium-Catalyzed Suzuki-Miyaura Cross-coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
Ruben Martin,Stephen L. Buchwald +1 more
TL;DR: An overview of the use and impact of dialkylbiarylphosphine ligands in the Suzuki-Miyaura cross-coupling reaction and the utility of these ligands has been successfully demonstrated in a wide number of synthetic applications, including industrially relevant processes.
Journal ArticleDOI
Catalytic functionalization of arenes and alkanes via C-H bond activation.
TL;DR: Several novel synthetic reactions of arenes and alkanes discovered and investigated in the laboratory are summarized here.
Journal ArticleDOI
Palladium-catalyzed carbonylation reactions of aryl halides and related compounds.
TL;DR: The recent academic developments in palladium-catalyzed carbonylation reactions of aromatic halides in the presence of various nucleophiles are summarized and the first industrial processes are summarized.
Journal ArticleDOI
The chemistry of dimethyl carbonate.
Pietro Tundo,Maurizio Selva +1 more
TL;DR: DMC possesses properties of nontoxicity and biodegradability which makes it a true green reagent to use in syntheses that prevent pollution at the source and avoiding the formation of undesirable inorganic salts as byproducts.
Journal ArticleDOI
Progress in hydroformylation and carbonylation
TL;DR: The last 15 years of hydroformylation and carbonylation chemistry are reviewed in this article, including technical and commercial aspects, and the authors present a review of the most relevant papers.