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Journal ArticleDOI

Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations

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This article is published in Chemical Reviews.The article was published on 2013-01-09. It has received 996 citations till now. The article focuses on the topics: Palladium.

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Citations
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3d Transition Metals for C-H Activation.

TL;DR: A comprehensive overview on first row transition metal catalysts for C-H activation until summer 2018 is provided.
Journal ArticleDOI

The Hitchhiker's Guide to Flow Chemistry

TL;DR: This review introduces readers to the basic principles and fundamentals of flow chemistry and critically discusses recent flow chemistry accounts.
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Basic concepts and recent advances in nitrophenol reduction by gold- and other transition metal nanoparticles

TL;DR: In this paper, the basic concepts and recent developments and advances of gold nanoparticle (AuNP)-catalyzed 4-nitrophenol (4-NP) reduction to 4-aminophenol by sodium borohydride, including the catalytic mechanism, the variety of stabilizers, and dendritic, natural and heterogeneous AuNP supports are presented.
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Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

TL;DR: The transition-metal-catalyzed addition of C-H bonds to carbonyls, imines, and related polarized π bonds has emerged as a particularly efficient and powerful approach for the construction of an incredibly diverse array of heteroatom-substituted products.
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Rh(III)- and Ir(III)-Catalyzed C-H Alkynylation of Arenes under Chelation Assistance

TL;DR: The current C-H alkynylation system complements those previously reported under gold or palladium catalysis using hypervalent iodine reagents and the synthetic applications of the coupled products have been demonstrated in subsequent derivatization reactions.
References
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Journal ArticleDOI

Green Chemistry: Principles and Practice

TL;DR: The concepts of design and the scientific philosophy of Green Chemistry are covered with a set of illustrative examples and the challenge of using the Principles as a cohesive design system is discussed.
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Palladium-catalyzed cross-coupling reactions in total synthesis.

TL;DR: In this Review, highlights of a number of selected syntheses are discussed, demonstrating the enormous power of these processes in the art of total synthesis and underscore their future potential in chemical synthesis.
Journal ArticleDOI

Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination

TL;DR: The application ofadium-catalyzed amination reactions of aryl halides in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceuticals, in materials science, and in natural product synthesis is discussed.
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