Journal ArticleDOI
Palladium-catalysed oxidation of primary and secondary alcohols
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This article is published in Tetrahedron.The article was published on 2003-07-28. It has received 377 citations till now. The article focuses on the topics: Palladium & Dehydrogenation.read more
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Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
Tamas Mallat,Alfons Baiker +1 more
TL;DR: It is considered more feasible that the rate-deter-mining step is the cleavage of the C-H bond at the R-carbon atom, and the active site consists of an ensemble of metallic Auatoms and a cationic Au.
Journal ArticleDOI
Fundamentals of green chemistry: efficiency in reaction design
TL;DR: The fundamental concepts underlying the principles of green and sustainable chemistry--atom and step economy and the E factor--are presented, within the general context of efficiency in organic synthesis, and the transition from fossil-based chemicals manufacture to a more sustainable biomass-based production is discussed.
Journal ArticleDOI
Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
TL;DR: Enantioselective PdII-catalyzed functionalization of alkenes has experienced considerably less success than have many other classes of enantiOSElective transformations, despite the extensive history of the Wacker process and related oxidation reactions.
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Size-specific catalytic activity of polymer-stabilized gold nanoclusters for aerobic alcohol oxidation in water.
TL;DR: A reaction mechanism for alcohol oxidation catalyzed by Au:PVP NCs is proposed in which a superoxo-like molecular oxygen species adsorbed on the surface of the small Au NCs abstracts a hydrogen atom from the alkoxide.
References
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Journal ArticleDOI
Reduced transition metal colloids: a novel family of reusable catalysts
Book
The organometallic chemistry of the transition metals
TL;DR: General Properties of Organometallic Complexes The Metal-Carbon and Metal-Hydrogen Bonds Ligand Substitution Reactions Complexes of Pi-Bound Ligands Oxidative Addition and Reductive Elimination Insertion and Elimination Nucleophilic and Electrophilic Additions and Abstraction Homogeneous Catalysis Characterization of OO Compounds Carbenes, Metathesis and Polymerization The Activation of Small Molecules Clusters and the Metal-Metal Bond Applications to Organic Synthesis Oxidation and High-Oxidation-State
Journal ArticleDOI
Green, catalytic oxidation of alcohols in water
TL;DR: A water-soluble palladium(II) bathophenanthroline complex is a stable recyclable catalyst for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic water-alcohol system.