Journal ArticleDOI
Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.
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This article is published in Journal of the American Chemical Society.The article was published on 2001-04-13. It has received 287 citations till now. The article focuses on the topics: Hydroamination & Palladium.read more
Citations
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Journal ArticleDOI
Hydroamination: direct addition of amines to alkenes and alkynes.
TL;DR: Hydroamination of Alkenes and Alkynes under Microwave Irradiation and Nitromercuration Reactions 3878 9.8.4.5.
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Late transition metal-catalyzed hydroamination and hydroamidation.
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Transition Metal‐Catalyzed Asymmetric Hydroamination of Alkenes (AHA)
TL;DR: A review of the state of the art in this rapidly evolving field of catalysis can be found in this paper, where the authors give an overview on the current state-of-the-art in chiral catalysts.
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Photosynthetic microbial mats in the 3,416-Myr-old ocean
Michael M. Tice,Donald R. Lowe +1 more
TL;DR: It is concluded that photosynthetic organisms had evolved and were living in a stratified ocean supersaturated in dissolved silica 3,416 Myr ago.
References
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Solid-State Coordination Chemistry: The Self-Assembly of Microporous Organic–Inorganic Hybrid Frameworks Constructed from Tetrapyridylporphyrin and Bimetallic Oxide Chains or Oxide Clusters
TL;DR: The hydrothermal reactions of MoO(3), tetrapyridylporphyrin (tpypor), water, and the appropriate M(II) precursor yield the first examples of three-dimensional framework materials constructed from metal oxide and porphyrin subunits.
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Reactive Organometallic Compounds Obtained from Metallocenes and Related Compounds and Their Synthetic Applications
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η3‐Allylpalladium Compounds
TL;DR: In this paper, a detailed study of the chemistry of the palladium-carbon bond was performed on η3-allylpalladium complexes, which are frequently involved as intermediates in the Pd-catalyzed transformations of dienes.
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The two component palladium catalyst system for intermolecular hydroamination of allenes
TL;DR: The combination of acetic acid with Pd2(dba)3 and dppf [1.11-Bis(diphenylphosphino ferrocene)] is a new type of catalytic system, capable of effecting the addition of protected and/or functionalized amines to allenes with high regio-and stereoselectivity as mentioned in this paper.
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Discovery of Novel Catalysts for Allylic Alkylation with a Visual Colorimetric Assay.
Olivier Lavastre,James P. Morken +1 more
TL;DR: The first non-phosphane iridium catalyst, made from [{IrCl(cod)}(2)] and iPr-pybox (shown schematically; cod=1,5-cyclooctadiene), for allylic alkylation in neutral medium was discovered by a simple, rapid, and inexpensive screening assay.