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Journal ArticleDOI

Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic

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TLDR
In this article, the authors conducted laboratory experiments for batch combustion/burning of commercial polymeric materials, simulating conditions of open fire combustion, with the purpose to analyze their emissions for chemical characteristics of toxicological importance.
About
This article is published in Journal of Hazardous Materials.The article was published on 2008-08-15. It has received 183 citations till now. The article focuses on the topics: Particulates & Soot.

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Citations
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Plastic Degradation and Its Environmental Implications with Special Reference to Poly(ethylene terephthalate)

TL;DR: A general overview of the current state of knowledge in areas that relate to biodegradation of polymers, especially poly(ethylene terephthalate) (PET), can be found in this paper.
Journal ArticleDOI

Toxic Pollutants from Plastic Waste- A Review

TL;DR: In this article, the hazards of incineration; open burning of plastics and effects of plastic in water and also a possibility of working out strategies to develop alternate procedures of plastic waste management.
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The valorization of plastic solid waste (PSW) by primary to quaternary routes: From re-use to energy and chemicals

TL;DR: In this article, the authors provide an in depth analysis regarding the recovery, treatment and recycling routes of plastic solid waste (PSW), as well as the main advantages and disadvantages associated with every route.
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Long-term phototransformation of microplastics under simulated sunlight irradiation in aquatic environments: Roles of reactive oxygen species.

TL;DR: The mechanism of formation of ROS by simulated solar light irradiated MPs and their subsequent roles in the phototransformation of MP are elucidated, thus expanding current knowledge on the fate of MPs in aquatic environments.
Journal ArticleDOI

Formation, characteristics, and applications of environmentally persistent free radicals in biochars: A review

TL;DR: In this paper, the formation mechanisms, characteristics, interactions, and environmental applications of surface-bound EPFRs in biochars are reviewed, and new and important insights into the fate and emerging applications of EPFR-mediated removal of organics/inorganics by bio-char are provided.
References
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MonographDOI

Electron Paramagnetic Resonance

TL;DR: In this paper, the authors measured the microwave power absorbed when the electrons transition to a higher energy state using the bridge circuit to quantify the absorption of photons from the electromagnetic field, which is known as the resonant frequency due to similarities the system shares with classical resonant systems.
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Quinoid redox cycling as a mechanism for sustained free radical generation by inhaled airborne particulate matter

TL;DR: It is hypothesized that semiquinone radicals in PM(2.5) undergo redox cycling, thereby reducing oxygen and generating reactive oxygen species while consuming tissue-reducing equivalents, such as NAD(P)H and ascorbate, which cause oxidative stress at sites of deposition and produce deleterious effects observed in the lung.
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Emissions of organic air toxics from open burning: a comprehensive review

TL;DR: In this article, a detailed literature search was performed to collect and collate available data reporting emissions of organic air toxics from open burning sources, including accidental fires, agricultural burning of Crop Residue, agricultural plastic film, animal carcasses, Automobile Shredder Fluff Fires, Camp Fires, Car- Boat-Train (the vehicle not cargo) Fires, Construction Debris Fires, Copper Wire Reclamation, Crude Oil and Oil Spill Fires, Electronics Waste, Fiberglass, Fireworks, Grain Silo Fires, Household Waste, Land Clearing
Journal ArticleDOI

Combustion Products of Plastics as Indicators for Refuse Burning in the Atmosphere

TL;DR: 1,3,5-Triphenylbenzene and tris(2,4-di-tert-butylphenyl)- phosphate were found in detectable amounts in atmospheric samples where plastics and refuse were burned in open fires, and thus it is proposed these two compounds as specific tracers for the open-burning of plastics.
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The Radicals in Cigarette Tar: Their Nature and Suggested Physiological Implications

TL;DR: The paramagnetism of cigarette tar is found to be associated with at least four different types of species, which indicates that the principal paramagnetic species in tar is not an organic monoradical (doublet) species but instead is a donor-acceptor excimer with a paramagnetic excited state and a diamagnetic ground state.
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