Journal ArticleDOI
.pi.-Bonded complexes of the tetraphenylborate ion with rhodium(I) and iridium(I)
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This article is published in Inorganic Chemistry.The article was published on 1970-10-01. It has received 322 citations till now. The article focuses on the topics: Tetraphenylborate & Iridium.read more
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Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds.
Keith Fagnou,Mark Lautens +1 more
Journal ArticleDOI
Transmetalation of Unsaturated Carbon Nucleophiles from Boron-Containing Species to the Mid to Late d-Block Metals of Relevance to Catalytic C−X Coupling Reactions (X = C, F, N, O, Pb, S, Se, Te)
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Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters.
TL;DR: A rhodium-catalyzed 1,4-addition of sodium tetraarylborates to beta, beta-disubstituted alpha,beta-unsaturated ketones is described, leading to the construction of quaternary carbon stereocenters with high enantioselectivity.
Journal ArticleDOI
Synthesis and Properties of Amino Acid-Based Polyacetylenes
TL;DR: In this article, the synthesis and polymerization of novel amino acid-derived acetylene monomers, N-(tert-butoxycarbonyl)-l-alanine N‘-propargylamide (L-1A), N-(TERt)-butoxy-carbonyl-l-alonine N
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Luminogenic Polyacetylenes and Conjugated Polyelectrolytes: Synthesis, Hybridization with Carbon Nanotubes, Aggregation-Induced Emission, Superamplification in Emission Quenching by Explosives, and Fluorescent Assay for Protein Quantitation
Wang Zhang Yuan,Hui Zhao,Xiao Yuan Shen,Faisal Mahtab,Jacky Wing Yip Lam,Jing Zhi Sun,Ben Zhong Tang,Ben Zhong Tang +7 more
TL;DR: In this article, an aggregation-induced emission enhancement (AIEE) effect was observed in the case of tetraphenylethene (TPE) units 1 and 2, where the TPE-functionalized luminogens are nonemissive in dilute solutions but luminescent as solid aggregates, showing a novel behavior of aggregationinduced emission.