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Plasma-Catalytic Partial Oxidation of Methane on Pt(111): A Microkinetic Study on the Role of Different Plasma Species
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In this article, microkinetic modeling was used to examine the potential of plasma-catalytic partial oxidation (POX) of CH4 as a promising new approach to produce oxygenates.Abstract:
We use microkinetic modeling to examine the potential of plasma-catalytic partial oxidation (POX) of CH4 as a promising new approach to produce oxygenates We study how different plasma species affread more
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Advances in non-equilibrium CO 2 plasma kinetics : a theoretical and experimental review
Lucia Daniela Pietanza,Olivier Guaitella,Vincenzo Aquilanti,I. Armenise,Annemie Bogaerts,Mario Capitelli,Gianpiero Colonna,Vasco Guerra,Richard Engeln,Elena Kustova,Andrea Lombardi,Federico Palazzetti,Tiago Silva +12 more
TL;DR: A review of the current state of knowledge on the physical chemistry of cold cold non-equilibrium plasmas is provided in this article, where the main findings of the latest zero-dimensional (0D) global models about the complex chemistry of the cold plasma and its dissociation products in different plasma discharges are given, and full state-to-state (STS) models of only the vibrational-dissociation kinetics developed for studies of spacecraft shields are described.
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Selective oxidation of CH4 to CH3OH through plasma catalysis: Insights from catalyst characterization and chemical kinetics modelling
Yanhui Yi,Yanhui Yi,Shangkun Li,Shangkun Li,Zhaolun Cui,Yingzi Hao,Yang Zhang,Li Wang,Pei Liu,Xin Tu,Xianming Xu,Hongchen Guo,Annemie Bogaerts +12 more
TL;DR: In this article, the selective oxidation of methane to methanol (SOMTM) by molecular oxygen is a holy grail in catalytic chemistry and remains a challenge in chemical industry.
Journal ArticleDOI
Energetics of Reaction Pathways Enabled by N and H Radicals during Catalytic, Plasma-Assisted NH3 Synthesis
TL;DR: In this article , the authors comprehensively examined, via density functional theory calculations, the energetics (favorability) of 51 reactions on Fe, Ni, Co, Pd, Ga, Sn, Cu, Au, and Ag.
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Foundations of plasma catalysis for environmental applications
TL;DR: In this paper , the fundamental insights in plasma catalysis, as well as efforts to gain more insights by modelling and experiments are described, and the state-of-the-art of the major plasma Catalysis applications are discussed.
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Reaction mechanism in non-thermal plasma enabled methane conversion: correlation between optical emission spectroscopy and gaseous products
TL;DR: In this paper, the reaction mechanism in non-thermal plasma enabled methane conversion driven by different sources, i.e., microwave discharge, nanosecond pulsed dielectric barrier discharge, and spark discharge, is investigated.
References
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Journal ArticleDOI
Dielectric-barrier Discharges: Their History, Discharge Physics, and Industrial Applications
TL;DR: In this article, the authors discuss the history, discharge physics, and plasma chemistry of dielectric-barrier discharges and their applications and discuss the applications of these discharges.
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Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects
TL;DR: This work focuses mainly on the fundamentals of C-H activation and analyzes the reaction pathways toward selective routes of OCM, MDA, and MTOAH to provide some insights into their reaction mechanisms and implications for future development of highly selective catalysts for direct conversion of methane to high value-added chemicals.
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A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts
TL;DR: In this article, an extensive table on contributions to catalytic partial oxidation of methane over transition metal catalysts in the literature is provided, and both theoretical and experimental evidence pointing to inherent differences in the reaction mechanism over transition metals.
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Plasma technology - a novel solution for CO2 conversion?
Ramses Snoeckx,Annemie Bogaerts +1 more
TL;DR: The current state-of-the-art and a critical assessment of plasma-based CO2 conversion, as well as the future challenges for its practical implementation are presented.
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Plasma Catalysis: Synergistic Effects at the Nanoscale
TL;DR: This Review critically examines the catalytic mechanisms relevant to each specific application of plasma catalysis, including CO2 conversion, hydrocarbon reforming, synthesis of nanomaterials, ammonia production, and abatement of toxic waste gases.