Journal ArticleDOI
Polymeric complexes of cadmium(II) bridged simultaneously by tetradentate picolinato and μ(1,1)-azido or μ(N,S)-thiocyanato anions. Synthesis and structural characterization of [Cd(picolinato)(N3)]n and [Cd(picolinato)(NCS)]n
TLDR
In this paper, two mixed ligand complexes of picolinic acid and cadmium(I I) azide or thiocyanate, namely catena-μ(1, 1)-azido-μ (N,O, O,O+,O′-picolinato)cadmium (II) (1) and catena μ(N,S)-thiocyclic-naphoric acid-thIocyanato-mixture-mixtures-mixed-ligand complexes (2) have been preparedAbout:
This article is published in Polyhedron.The article was published on 1997-01-01. It has received 52 citations till now. The article focuses on the topics: Carboxylate.read more
Citations
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Synthesis and crystal structure of thiocyanato or azido bridged one- or two-dimensional polymeric complexes of cadmium(II)
TL;DR: In this article, four new polymeric complexes [Cd(dmen)(SCN)2]n 1, [cd(deen) 2]n 2, [Ccdrn)(N3]n 3]n 4 and [Cdrn(deen)-N3]-n 4 have been synthesized and characterized by single crystal X-ray diffraction.
Journal ArticleDOI
Synthesis and crystal structure of three new 2D polymeric cadmium(II) complexes of some pyridine derivatives with different cadmium(II)–azide topologies
TL;DR: In this article, three new polymeric complexes [Cd(2-Acpy)(N3)2]n1, [cd(4-acpy)2 n3]n2 and [Ccd3 nbrpy)4 n3 6]n3 have been synthesized and characterized by single crystal X-ray diffraction, and the coordination environment of the cadmium atom is distorted octahedral with two-dimensional polynuclear layers.
Journal ArticleDOI
Two new polymeric cadmium(II) complexes containing end-to-end bridging azido or thiocyanato ligands with different topologies
Mohamed A. S. Goher,Franz A. Mautner,Afaf K. Hafez,Morsy A. M. Abu-Youssef,Christian Gspan,Ahmed M.A. Badr +5 more
TL;DR: In this article, two polymeric cadmium(II) complexes, [Cd(3,5-DMP)2(N3)2] (1) and [cd(4-Brpy)2 (NCS) 2] (2), have been synthesized and characterized.
Journal ArticleDOI
Three novel Cu(II), Cd(II) and Cr(III) complexes of 6−Methylpyridine−2−carboxylic acid with thiocyanate: Synthesis, crystal structures, DFT calculations, molecular docking and α-Glucosidase inhibition studies
Davut Avcı,Sümeyye Altürk,Fatih Sonmez,Ömer Tamer,Adil Başoğlu,Yusuf Atalay,Belma Zengin Kurt,Necmi Dege +7 more
TL;DR: In this paper, a novel 6−methylpyridine−2−carboxylic acid and thiocyanate complexes were synthesized, and their structures were characterized by XRD analysis, FT-IR and UV-Vis spectroscopic techniques.
Journal ArticleDOI
Assembly of a helical zinc(II) chain and a two-dimensional cadmium(II) coordination polymer using picolinate and sulfate anions as bridging ligands
Constantina Papatriantafyllopoulou,Catherine P. Raptopoulou,Aris Terzis,Jozef F. Janssens,Evy Manessi-Zoupa,Spyros P. Perlepes,John C. Plakatouras +6 more
TL;DR: In this article, the initial use of the picolinate (pic−)/sulfate "blend" in metal chemistry has yielded two neutral coordination polymers, Zn2(SO4)(pic)2(H2O)3]n (1) and Cd2(Cd, x = 8/3) in aqueous solution in the absence of external base.
References
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International tables for X-ray crystallography
Norman Fordyce McKerron Henry,Lonsdale, Kathleen, Dame,John S. Kasper,Caroline H. MacGillavry,Gerard D. Rieck,James A. Ibers,Walter C. Hamilton +6 more
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Infrared spectra of complexes of the thiocyanate and related ions
Journal ArticleDOI
Infrared absorption spectra of aquo complexes and the nature of co-ordination bonds
TL;DR: In this paper, a normal co-ordinate treatment has been made for one complex ion of T h symmetry and for D 4 h symmetry on the basis of Urey-Bradley type potential and the bond stretching force constants for the various metal-oxygen bonds have been calculated.
Journal ArticleDOI
Crystal structure and magnetic and EPR properties of bis(.mu.-azido)tetrakis(4-tert-butylpyridine)dicopper(II) perchlorate: a new copper(II) dinuclear complex with a large stabilization of the ground triplet state
TL;DR: Cristallisation dans le groupe P2 1 /c avec a=12,819, b=13,76, and c= 13,65 A, β=100°, Z=2.