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Journal ArticleDOI

Polypyridine transition metal complexes as light emission sensitizers in the electrochemical reduction of the persulfate ion

TLDR
In this article, the reduction of polypyridine-type complexes of Cr(III, Ru(II), and Os(II) in the presence of S2O82− ions is accompanied by light emission.
About
This article is published in Inorganica Chimica Acta.The article was published on 1982-01-01. It has received 61 citations till now. The article focuses on the topics: Polypyridine complex & Light emission.

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Citations
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Journal ArticleDOI

Electrogenerated Chemiluminescence and Its Biorelated Applications

TL;DR: ECL has now become a very powerful analytical technique and been widely used in the areas of immunoassay, food and water testing, and biowarfare agent detection and has also been successfully exploited as a detector of flow injection analysis (FIA), high-performance liquid chromatography (HPLC), capillary electrophoresis, and micro total analysis (μTAS).
Book ChapterDOI

Photochemistry and Photophysics of Coordination Compounds: Ruthenium

TL;DR: In this paper, the photochemical properties of Ru(II) polypyridine complexes are discussed and an overview of various research topics involving ruthenium photochemistry which have emerged in the last 15 years are discussed.
Journal ArticleDOI

Recent applications of electrogenerated chemiluminescence in chemical analysis.

TL;DR: Analytical applications of electrogenerated chemiluminescence (ECL) are reviewed with emphasis on the years 1997-2000 and new developments and improvements of techniques and instrumentation and their application to analytes are described.
Journal ArticleDOI

Photochemistry and photophysics of Ru(II)polypyridine complexes in the Bologna group. From early studies to recent developments

TL;DR: In this article, a review of the investigations carried out in the Bologna group on Ru(bpy)32+ (bpy=2,2′-bipyridine) and related systems are reviewed.
References
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Journal ArticleDOI

Electrogenerated chemiluminescence. IX. Electrochemistry and emission from systems containing tris(2,2'-bipyridine)ruthenium(II) dichloride

TL;DR: Tokel et al. as mentioned in this paper investigated the emission from tris(2,2'-bipyridine)ruthenium(II) dichloride systems and found that tris (2, 2-biprithmidine) is more stable than tris((2,1)-biprinidine)R. Am. Chem., 1972, 94 (8), 2862-2863.
Journal ArticleDOI

Electrogenerated chemiluminescence. 37. Aqueous ecl systems based on tris(2,2'-bipyridine)ruthenium(2+) and oxalate or organic acids

TL;DR: In this article, an aqueous system for electrogenerated chemiluminescence (ecl) based on the reaction of electregenerated Ru(bpy),'+ with strong reductants produced as intermediates in the oxidation of oxalate ion is described.
Journal ArticleDOI

Mechanism of the Electrochemical Reduction of Persulfates and Hydrogen Peroxide

TL;DR: In this paper, it was shown from corresponding measurements performed with a semiconductor electrode that the electrochemical properties of persulfate and hydrogen peroxide have to be described by two instead of one redox (normal) potential.
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