Journal ArticleDOI
Relaxation-induced violations of coherence transfer selection rules in nuclear magnetic resonance
Reads0
Chats0
TLDR
The effect of multiexponential transverse relaxation of degenerate transitions on coherence transfer phenomena in high-resoln. NMR is discussed in this paper, and the implications for multiple-quantum-filtered 2-dimensional correlation spectra of large mols are analyzed.About:
This article is published in Journal of Magnetic Resonance.The article was published on 1987-11-01. It has received 157 citations till now. The article focuses on the topics: Relaxation (NMR) & Spin–spin relaxation.read more
Citations
More filters
Journal ArticleDOI
NMR studies of protein structure and dynamics
TL;DR: Examples where millisecond time scale dynamics play an important role and where relaxation dispersion NMR spectroscopy has been particularly informative, including applications involving the membrane enzyme PagP and mutants of the Fyn SH3 domain that fold on a ms time scale, are presented.
Journal ArticleDOI
Sodium and T1ρ MRI for molecular and diagnostic imaging of articular cartilage
Arijitt Borthakur,Eric A. Mellon,Sampreet Niyogi,Walter R Witschey,J. Bruce Kneeland,Ravinder Reddy +5 more
TL;DR: Both sodium magnetic resonance (MR) and T1ρ relaxation mapping aimed at measuring molecular changes in cartilage for the diagnostic imaging of osteoarthritis are reviewed.
Journal ArticleDOI
Nuclear magnetic resonance spectroscopy of high-molecular-weight proteins.
TL;DR: The utility of the new methodology in NMR spectroscopy is illustrated by considering applications to malate synthase G, a 723 residue enzyme, which is the largest single polypeptide chain for which chemical shift assignments have been obtained to date.
Journal ArticleDOI
An Isotope Labeling Strategy for Methyl TROSY Spectroscopy
Vitali Tugarinov,Lewis E. Kay +1 more
TL;DR: It is shown that excellent quality methyl TROSY spectra can be recorded on U-[2H] Ileδ1-[ 13CH3] Leu,Val-[13CH3/12CD3] protein samples, significantly extending the number of probes available for structural and dynamic studies of high molecular weight systems.
Journal ArticleDOI
Solid-State Li NMR with Applications to the Translational Dynamics in Ion Conductors
TL;DR: In this paper, the influence of motion on one-dimensional spectra was studied and the effects of spin evolution in the presence of homonuclear dipolar interactions on radio-frequency pulses.
References
More filters
Angular Momentum in Quantum Mechanics
TL;DR: In this paper, the angular momentum, one of the most fundamental quantities in all of quantum mechanics, is introduced and a concise introduction to its application in atomic, molecular, and nuclear physics is provided.
Book
Angular Momentum in Quantum Mechanics
TL;DR: In this article, the angular momentum, one of the most fundamental quantities in all of quantum mechanics, is introduced and a concise introduction to its application in atomic, molecular, and nuclear physics is provided.
Journal ArticleDOI
Two‐dimensional spectroscopy. Application to nuclear magnetic resonance
TL;DR: In this article, the possibilities for the extension of spectroscopy to two dimensions are discussed, including the elucidation of energy level diagrams, the observation of multiple quantum transitions, and the recording of high-resolution spectra in inhomogenous magnetic fields.
Journal ArticleDOI
Improved spectral resolution in cosy 1H NMR spectra of proteins via double quantum filtering.
TL;DR: The elimination of the dispersive character of the diagonal peaks in phase-sensitive, double quantum-filtered COSY spectra allows identification of cross peaks lying immediately adjacent to the diagonal, which represents a significant improvement over the conventional COSy experiment.