Journal ArticleDOI
Restraining Symmetry in the Formation of Small Polyoxomolybdates: Building Blocks of Unprecedented Topology Resulting from “Shrink‐Wrapping” [H2Mo16O52]10‐‐Type Clusters.
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This article is published in ChemInform.The article was published on 2003-11-25. It has received 2 citations till now. The article focuses on the topics: Topology (chemistry).read more
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Beyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry
TL;DR: How application‐inspired research has exploited cation‐controlled design to discover new POM materials has led to the quest for fundamental understanding of POM–cation interactions is explored.
Journal ArticleDOI
O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution.
Yang Yang,Yumin Qian,Haijing Li,Zhenhua Zhang,Yue-Wen Mu,David Do,Bo Zhou,Dong Jing,Wenjun Yan,Yong Qin,Li Fang,Renfei Feng,Jigang Zhou,Peng Zhang,Juncai Dong,Guihua Yu,Yuanyue Liu,Xian-Ming Zhang,Xian-Ming Zhang,Xiujun Fan,Xiujun Fan +20 more
TL;DR: A dual-atom catalyst consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (W1Mo1-NG), which is synthesized by controllable self-assembly and nitridation processes that enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte.
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Journal ArticleDOI
Restraining symmetry in the formation of small polyoxomolybdates: building blocks of unprecedented topology resulting from "shrink-wrapping" [H2Mo16O52]10--type clusters.
TL;DR: A mixed-valence polyoxomolybdate cluster was isolated by a new “shrink-wrapping” approach to trap clusters that display low symmetry and nonspherical topology, yet it reacts with electrophiles, such as FeII.