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Open AccessJournal ArticleDOI

Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism

TLDR
In this article, the synthesis, characterization, and catalytic performance for gas phase propane dehydrogenation of single-site Co2+ ions supported on silica was reported.
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This article is published in Journal of Catalysis.The article was published on 2015-02-01 and is currently open access. It has received 160 citations till now. The article focuses on the topics: Dehydrogenation & Extended X-ray absorption fine structure.

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The investigation into the different Co species over Silicalite-1 via modulating heat-treatment atmosphere for propane dehydrogenation

TL;DR: In this paper , different Co species over Silicalite-1 are synthesized via modulating heat-treatment atmosphere and investigated for propane dehydrogenation systematically, and it is confirmed that the highly dispersed tetrahedral coordinated Co 2+ species incorporated into SilicalITE-1 framework with Lewis acid sites over Co-S-1-Ar is responsible for the superior PDH performance, while bulk aggregated Co 3 O 4 species in Co/S 1-Air has much lower catalytic performance.
Journal ArticleDOI

Steam Reforming of Ethanol on Ferrites

TL;DR: In this article, the results of the investigations of steam reforming of ethanol (SRE) on nanosized ferrites with spinel structure MFe2O4 (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) are summarized.
Journal ArticleDOI

Effect of Reduction Atmosphere on Structure and Catalytic Performance of PtIn/Mg(Al)O/ZnO for Propane Dehydrogenation

TL;DR: In this article, the effect of reduction atmospheres, H2/N2, C3H8/H2N2 and CO on the structure and propane direct dehydrogenation performance of PtIn/Mg(Al)O/ZnO catalyst derived from ZnO-supported PtIn-hydrotalcite was studied.
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CO2 assisted ethane dehydrogenation over Co-exchanged ZSM-5 and ZSM-11 zeolites: Effect of Al spatial distribution

TL;DR: In this article , a series of cobalt catalysts loaded on ZSM5 and ZSM-11 zeolites with different aluminum spatial distribution were prepared by wet ion-exchanged method and characterized by XRD, N2 adsorption, SEM, 27Al MAS NMR, H2-TPR, Py-IR, XPS and diffuse reflectance UV-vis.
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Influence of carbonization temperature on cobalt-based nitrogen-doped carbon nanopolyhedra derived from ZIF-67 for nonoxidative propane dehydrogenation

TL;DR: In this article , Nitrogen-doped carbon (NC) nanopolyhedra supported cobalt catalysts were synthesized in one-step of ZIF-67 pyrolysis and investigated further in PDH.
References
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Journal ArticleDOI

Density‐functional thermochemistry. III. The role of exact exchange

TL;DR: In this article, a semi-empirical exchange correlation functional with local spin density, gradient, and exact exchange terms was proposed. But this functional performed significantly better than previous functionals with gradient corrections only, and fits experimental atomization energies with an impressively small average absolute deviation of 2.4 kcal/mol.
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Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides

TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
Journal ArticleDOI

Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr

TL;DR: In this article, a triple zeta valence (TZV) basis set is presented for Li to Kr. The TZV bases are characterized by typically including a single contraction to describe inner shells and three basis functions for valence shells.
Book

Comprehensive handbook of chemical bond energies

TL;DR: In this article, experimental methods for measuring BDEs are presented for measuring C-H bonds, C-C bonds, and C -C-C-H-C Bonds.
Journal ArticleDOI

Catalytic dehydrogenation of light alkanes on metals and metal oxides.

TL;DR: The study compares different catalysts in terms of the reaction mechanism and deactivation pathways and catalytic performance, as dehydrogenation for the production of light olefins has become extremely relevant.
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