Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism
Bo Hu,Bo Hu,Andrew “Bean” Getsoian,Neil M. Schweitzer,Neil M. Schweitzer,Ujjal Das,Hacksung Kim,Hacksung Kim,Jens Niklas,Oleg G. Poluektov,Larry A. Curtiss,Peter C. Stair,Peter C. Stair,Jeffrey T. Miller,Adam S. Hock,Adam S. Hock +15 more
TLDR
In this article, the synthesis, characterization, and catalytic performance for gas phase propane dehydrogenation of single-site Co2+ ions supported on silica was reported.About:
This article is published in Journal of Catalysis.The article was published on 2015-02-01 and is currently open access. It has received 160 citations till now. The article focuses on the topics: Dehydrogenation & Extended X-ray absorption fine structure.read more
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Supported Aluminum Catalysts for Olefin Hydrogenation
Jeffrey Camacho-Bunquin,Magali Ferrandon,Ujjal Das,Fulya Dogan,Cong Liu,Casey R. Larsen,Ana E. Platero-Prats,Larry A. Curtiss,Adam S. Hock,Adam S. Hock,Jeffrey T. Miller,SonBinh T. Nguyen,SonBinh T. Nguyen,Christopher L. Marshall,Massimiliano Delferro,Peter C. Stair,Peter C. Stair +16 more
TL;DR: In this article, three-coordinate alkylaluminum sites were developed on a catechol-containing porous organic polymer support (CatPOP A2B1), which can hydrogenate and isomerize a range of mono-and disubstituted alkenes and alkynes under mild conditions.
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Activation of C−F Bonds by Electrophilic Organosilicon Sites Supported on Sulfated Zirconia
TL;DR: Solid-state NMR studies of the organosilicon functionalized SZO shows that electrophilic [TIPS][SZO] sites are present on the surface, in addition to less reactive TIPS-Ox and SiOx species.
Journal ArticleDOI
MOF-Derived Iron Catalysts for Nonoxidative Propane Dehydrogenation
TL;DR: The dehydrogenation of light alkanes, sourced from cracking of traditional petrochemical feedstocks and from emerging shale gas, represents an attractive route to alkenes (ethene, propene, and bute....
Journal ArticleDOI
Construction of Spatial Effect from Atomically Dispersed Co Anchoring on Subnanometer Ru Cluster for Enhanced N2-to-NH3 Conversion
Yangyu Zhang,Jiejie Li,Jihui Cai,Linlin Yang,Tianhua Zhang,Jianxin Lin,Xiuyun Wang,Chongqi Chen,Lirong Zheng,Chak-Tong Au,Bo Yang,Lilong Jiang +11 more
TL;DR: Simultaneously achieving a low activation barrier with weak binding of intermediates on a heterogeneous catalyst for the enhancement of catalytic performance under mild conditions remains a great c... as mentioned in this paper,.
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Effect of pH on the catalytic performance of PtSn/B-ZrO2 in propane dehydrogenation
TL;DR: In this paper, Boron-modified ZrO2 (B-ZrO 2) was synthesized under various pH values (9, 10, and 11) and used as the supports of PtSn catalysts for nonoxidative dehydrogenation of propane.
References
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Journal ArticleDOI
Density‐functional thermochemistry. III. The role of exact exchange
TL;DR: In this article, a semi-empirical exchange correlation functional with local spin density, gradient, and exact exchange terms was proposed. But this functional performed significantly better than previous functionals with gradient corrections only, and fits experimental atomization energies with an impressively small average absolute deviation of 2.4 kcal/mol.
Journal ArticleDOI
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
Journal ArticleDOI
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr
TL;DR: In this article, a triple zeta valence (TZV) basis set is presented for Li to Kr. The TZV bases are characterized by typically including a single contraction to describe inner shells and three basis functions for valence shells.
Book
Comprehensive handbook of chemical bond energies
TL;DR: In this article, experimental methods for measuring BDEs are presented for measuring C-H bonds, C-C bonds, and C -C-C-H-C Bonds.
Journal ArticleDOI
Catalytic dehydrogenation of light alkanes on metals and metal oxides.
TL;DR: The study compares different catalysts in terms of the reaction mechanism and deactivation pathways and catalytic performance, as dehydrogenation for the production of light olefins has become extremely relevant.