Journal ArticleDOI
Selenium-catalyzed nonradical chlorination of olefins with N-chlorosuccinimide
Tetsuo Hori,K. Barry Sharpless +1 more
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This article is published in Journal of Organic Chemistry.The article was published on 1979-11-01. It has received 58 citations till now. The article focuses on the topics: Selenium.read more
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An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes
Gregory S. Sauer,Song Lin +1 more
TL;DR: In this article, the design principles underpinning the development of electrochemical diazidation, dichlorination, and halotrifluoromethylation of alkenes were described.
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Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources
TL;DR: Mechanistic data are consistent with metal-mediated Cl atom transfer as the predominant pathway enabling dual C-Cl bond formation and contradict an alternative pathway involving electrochemical evolution of chlorine gas followed by Cl2-mediated electrophilic dichlorination.
Journal ArticleDOI
Catalytic, stereospecific syn-dichlorination of alkenes
TL;DR: The first catalytic, syn-stereospecific dichlorination of alkenes, employing a redox-active main group element as a group transfer catalyst is described.
Journal ArticleDOI
Organoselenium-induced cyclizations in organic synthesis
TL;DR: In this paper, a number of organoselenium reagents are introduced as efficient initiators of ring closures leading from unsaturated substrates to lactones, cyclic ethers and cyclic thioethers.
Journal ArticleDOI
Selenium reagents as catalysts
Fateh V. Singh,Thomas Wirth +1 more
TL;DR: In this paper, a review of recently developed selenium-catalyzed reactions are covered including stereoselective reactions, and a number of organic and inorganic oxidants have been employed to regenerate different active catalytic species in situ.
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Fateh V. Singh,Thomas Wirth +1 more