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SERS substrate for detection of explosives

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TLDR
In this paper, a gold-coated femtosecond laser nanostructured sapphire surface was used to detect taggants in explosives, which can undertake as part of an integrated security or investigative mission.
Abstract
A novel gold coated femtosecond laser nanostructured sapphire surface – an “optical nose” – based on surface-enhanced Raman spectroscopy (SERS) for detecting vapours of explosive substances was investigated. Four different nitroaromatic vapours at room temperature were tested. Sensor responses were unambiguous and showed response in the range of 0.05–15 μM at 25 °C. The laser fabricated substrate nanostructures produced up to an eight-fold increase in Raman signal over that observed on the unstructured portions of the substrate. This work demonstrates a simple sensing system that is compatible with commercial manufacturing practices to detect taggants in explosives which can undertake as part of an integrated security or investigative mission.

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Journal ArticleDOI

Review of SERS Substrates for Chemical Sensing.

TL;DR: A review of the most common metallic SERS substrates for chemical detection only is discussed, as well as SERS paradigms that are commercially available that have been addressed.
Journal ArticleDOI

Explosive and chemical threat detection by surface-enhanced Raman scattering: A review

TL;DR: The prospects of SERS becoming a major tool for convenient in-situ threat identification and existing SERS detection methods and substrates are discussed, with particular focus on ultra-sensitive real-time detection.
Journal ArticleDOI

Recent progress in surface enhanced Raman spectroscopy for the detection of environmental pollutants

TL;DR: The surface enhanced Raman spectroscopy (SERS) has emerged as one of the most promising analytical tools in recent years as mentioned in this paper. But its performance has not yet reached the state-of-the-art.
Journal ArticleDOI

Detection of heavy metal ions in contaminated water by surface plasmon resonance based optical fibre sensor using conducting polymer and chitosan

TL;DR: The cadmium ions bind strongly to the sensing surface than other ions and due to this the sensor is highly sensitive for Cd(2+) ions.
References
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Journal ArticleDOI

Optical Constants of the Noble Metals

TL;DR: In this paper, the optical constants for the noble metals (copper, silver, and gold) from reflection and transmission measurements on vacuum-evaporated thin films at room temperature, in the spectral range 0.5-6.5 eV.
Journal ArticleDOI

Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS)

TL;DR: In this article, the first observation of single molecule Raman scattering was made using a single crystal violet molecule in aqueous colloidal silver solution using one second collection time and about $2.
Journal ArticleDOI

Raman spectra of pyridine adsorbed at a silver electrode

TL;DR: In this article, Ramaman spectroscopy has been employed for the first time to study the role of adsorption at electrodes, and it has been possible to distinguish two types of pyridine adaption at a silver electrode.
Journal ArticleDOI

Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode

TL;DR: In this article, the authors verified the remarkable sensitivity of Raman spectroscopy for the study of adsorbed pyridine on a silver surface, and extended its applicability to other nitrogen heterocycles and amines.
Journal ArticleDOI

Femtosecond laser micromachining in transparent materials

TL;DR: In this article, the physical mechanisms and the main experimental parameters involved in femtosecond laser micromachining of transparent materials, and important emerging applications of the technology are described.
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